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Iodido[1-(propan-2-yl-idene)thio-semi-carbazide-?S]bis-(triphenyl-phosphane-?P)copper(I).


ABSTRACT: In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra-hedral coordination geometry involving two P atoms of two triphenyl-phosphane mol-ecules, one S atom of a 1-(propan-2-yl-idene)thio-semicarbazide mol-ecule and one iodide ion. In the crystal, C-H?? inter-actions [C-H?centroid distances = 3.443?(3) and 3.788?(3)?Å] and N-H?S hydrogen bonds form layers parallel to (100). An intra-molecular N-H?I hydrogen bond is also observed.

SUBMITTER: Wattanakanjana Y 

PROVIDER: S-EPMC3515154 | biostudies-other | 2012 Nov

REPOSITORIES: biostudies-other

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Iodido[1-(propan-2-yl-idene)thio-semi-carbazide-κS]bis-(triphenyl-phosphane-κP)copper(I).

Wattanakanjana Yupa Y   Pakawatchai Chaveng C   Saithong Saowanit S   Piboonphon Prapaporn P   Nimthong Ruthairat R  

Acta crystallographica. Section E, Structure reports online 20121031 Pt 11


In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra-hedral coordination geometry involving two P atoms of two triphenyl-phosphane mol-ecules, one S atom of a 1-(propan-2-yl-idene)thio-semicarbazide mol-ecule and one iodide ion. In the crystal, C-H⋯π inter-actions [C-H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N-H⋯S hydrogen bonds form layers parallel to (100). An intra-molecular N-H⋯I hydrogen bond is also observed. ...[more]

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