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ABSTRACT:
SUBMITTER: Haehnel M
PROVIDER: S-EPMC3515160 | biostudies-other | 2012 Nov
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20121031 Pt 11
The title dimeric zirconium complex, [Zr(2)(C(20)H(24))(2)S(2)]·C(7)H(8), was obtained from the reaction of (ebthi)Zr(η(2)-Me(3)Si-C(2)-SiMe(3)) [ebthi is rac-1,2-bis-(η(5)-4,5,6,7-tetra-hydro-inden-1-yl)ethane] and S=C=N-ada (ada = adamantan-1-yl) along with the formation of the isonitrile C N-ada. Each Zr(IV) atom is coordinated by the sterically hindered ebthi ligand and two μ-sulfide ligands in a strongly distorted tetra-hedral geometry. The [ZrS](2) unit is almost planar (mean deviation fro ...[more]