Unknown

Dataset Information

0

[(E)-1-(Naph-thalen-2-yl)ethyl-idene](naph-thalen-1-ylmethyl)amine.

ABSTRACT: The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho-yl)-3,3,3-trifluoro-acetone and PzPy = 2-[3(5)-pyrazol-yl]pyridine} with 1-naphthyl-methyl-amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 and 0.011?Å, respectively] and subtend angles of 38.69?(11) and 16.50?(11)°, respectively, with the central CH(3)-C=N-CH(2) unit, which is also almost planar [r.m.s. deviation = 0.002?Å]. In the crystal, the mol-ecules are disposed in zigzag-type fashion, forming layers perpendicular to [100]. Weak supra-molecular C-H?? inter-actions contribute to the packing forces.

SUBMITTER: Bruno SM 

PROVIDER: S-EPMC3515244 | biostudies-other | 2012 Nov

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

[(E)-1-(Naph-thalen-2-yl)ethyl-idene](naph-thalen-1-ylmethyl)amine.

Bruno Sofia M SM   Fernandes José A JA   Gonçalves Isabel S IS   Almeida Paz Filipe A FA  

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho-yl)-3,3,3-trifluoro-acetone and PzPy = 2-[3(5)-pyrazol-yl]pyridine} with 1-naphthyl-methyl-amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 and 0.011 Å, respectively] and subtend angles of 38.69 (11) and 16.50 (11)°, respectively, with the central CH(3)-C=N-CH(2) unit, which is also almost planar [r.m.s. deviation = 0.002 Å]. In the crystal  ...[more]

Similar Datasets

Unknown (E)-Benz-yl(1-phenyl-ethyl-idene)amine.
| S-EPMC3793782 | biostudies-literature
Unknown (S)-(+)-N-Benzyl-idene-1-(1-naphth-yl)ethyl-amine.
| S-EPMC3089063 | biostudies-literature
Unknown N-[1-(2-Hydroxy-phen-yl)ethyl-idene]-N-(1H-indol-3-ylmethyl-ene)carbonic dihydrazide.
| S-EPMC2960057 | biostudies-literature
Unknown N-[(E)-Quinoxalin-2-ylmethyl-idene]-1H-indazol-5-amine.
| S-EPMC2977485 | biostudies-literature
Unknown (+)-(S)-N-[(1-Benzo-thio-phen-2-yl)methyl-idene]-1-(naphthalen-1-yl)ethyl-amine.
| S-EPMC3884384 | biostudies-literature
Unknown N-[(9-Ethyl-9H-carbazol-3-yl)methyl-idene]-3,4-dimethyl-isoxazol-5-amine.
| S-EPMC3007468 | biostudies-literature
Unknown Tris[2-(pyrrol-2-ylmethyl-eneamino)eth-yl]amine.
| S-EPMC2960820 | biostudies-other
Unknown Poly[[diaqua-{N-[1-(3-pyrid-yl)ethyl-idene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis-(perchlorate)].
| S-EPMC2977576 | biostudies-literature
Unknown Tris{2-[(3-thien-yl)methyl-idene-amino]-eth-yl}amine.
| S-EPMC3009092 | biostudies-literature
Unknown 9-Ethyl-N-(3-nitro-benzyl-idene)-9H-carbazol-3-amine.
| S-EPMC3151935 | biostudies-literature