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Catena-Poly[(acetato-chloridozinc)-?-1,1'-[1,4-phenyl-enebis(methyl-ene)]di-1H-imidazole].

ABSTRACT: The title compound, [Zn(CH(3)CO(2))Cl(C(14)H(14)N(4))](n), is a one-dimensional coordination polymer in which the Zn(II) ion is tetrahedrally -coordinated by two N atoms of a bridging 1,1'-[1,4-phenyl-enebis(methyl-ene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetate O atoms and two acetate C atoms are located on a mirror plane. The coordination of the diimidazole ligand to the Zn(II) ion gives an infinite one-dimensional zigzag structure along the b-axis direction with the charge balanced by the chloride and acetate ions.

SUBMITTER: Wang L

PROVIDER: S-EPMC3569199 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other

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catena-Poly[(acetato-chloridozinc)-μ-1,1'-[1,4-phenyl-enebis(methyl-ene)]di-1H-imidazole].

Wang Liang L

Acta crystallographica. Section E, Structure reports online 20130112 Pt 2

The title compound, [Zn(CH(3)CO(2))Cl(C(14)H(14)N(4))](n), is a one-dimensional coordination polymer in which the Zn(II) ion is tetrahedrally -coordinated by two N atoms of a bridging 1,1'-[1,4-phenyl-enebis(methyl-ene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetate O atoms and two acetate C atoms are located on a mirror plane. The coordination of the diimidazole ligand to the Zn(II) ion gives an infinite one-dimensional zigzag structure along the b-axis direct ...[more]

PMID: 23424400

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Crystal structure of catena-poly[bis(formato-κO)bis-[μ2-1,1'-(1,4-phenyl-ene)bis-(1H-imidazole)-κ(2) N (3):N (3')]cobalt(II)].

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