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Tetra-methyl-ammonium aqua-trichlorido-oxalatostannate(IV) monohydrate.

ABSTRACT: The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa-hedral. The anions are connected by the lattice water mol-ecule through O-H?O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C-H?O and C-H?Cl inter-actions.

SUBMITTER: Sow Y 

PROVIDER: S-EPMC3569201 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other

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Tetra-methyl-ammonium aqua-trichlorido-oxalatostannate(IV) monohydrate.

Sow Yaya Y   Diop Libasse L   Molloy Kieran C KC   Kociok-Köhn Gabriele G  

Acta crystallographica. Section E, Structure reports online 20130116 Pt 2

The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol-ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa-hedral. The anions are connected by the lattice water mol-ecule through O-H⋯O hydrogen bonds, leading to a layered structure parallel to (010).  ...[more]

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