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Cis-Dichlorido(dimethyl sulfoxide-?S)(N,N,N',N'-tetra-methyl-guanidine-?N'')platinum(II).

ABSTRACT: In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-H?O hydrogen bond.

SUBMITTER: Eliseev II

PROVIDER: S-EPMC3569208 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other

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cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N',N'-tetra-methyl-guanidine-κN'')platinum(II).

Eliseev Ivan I II Bokach Nadezhda A NA Haukka Matti M Golenya Irina A IA

Acta crystallographica. Section E, Structure reports online 20130119 Pt 2

In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an ...[more]

PMID: 23424410

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