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1-{(Z)-[2-Meth-oxy-5-(trifluoro-meth-yl)anilino]methyl-idene}naphthalen-2(1H)-one.

ABSTRACT: The title compound, C(19)H(14)F(3)NO(2), crystallizes in the keto-amine tautomeric form, with a strong intra-molecular N-H?O hydrogen bond. The mol-ecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60?(7)°. In the crystal, mol-ecules are linked into chains along the c axis by C-H?O hydrogen bonds. The F atoms of the trifluoro-methyl group are disordered over two positions with refined site occupancies of 0.668?(9) and 0.332?(9).

SUBMITTER: Karg?l? H

PROVIDER: S-EPMC3569228 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other

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1-{(Z)-[2-Meth-oxy-5-(trifluoro-meth-yl)anilino]methyl-idene}naphthalen-2(1H)-one.

Kargılı Hakan H Alaman Ağar Ayşen A Alpaslan Gökhan G Büyükgüngör Orhan O Erdönmez Ahmet A

Acta crystallographica. Section E, Structure reports online 20130104 Pt 2

The title compound, C(19)H(14)F(3)NO(2), crystallizes in the keto-amine tautomeric form, with a strong intra-molecular N-H⋯O hydrogen bond. The mol-ecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60 (7)°. In the crystal, mol-ecules are linked into chains along the c axis by C-H⋯O hydrogen bonds. The F atoms of the trifluoro-methyl group are disordered over two positions with refined site occupancies of 0.668 (9) and 0.332 (9). ...[more]

PMID: 23424451

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