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Trans-Di-?-chlorido-bis-{chlorido[tris-(3,5-dimethyl-phen-yl)phosphane-?P]palla-dium(II)} dichloro-methane monosolvate.

ABSTRACT: In the dimeric title compound, [Pd2Cl4{P(C8H9)3}2]·CH2Cl2, the metal complex molecule is situated about an inversion centre and is accompanied by a dichloro-methane solvent mol-ecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris-(3,5-dimethyl-phen-yl)phos-phane ligand was calculated to be 169°. In the crystal, the metal complex and solvent mol-ecules are linked via C-H?Cl inter-actions, generating chains along [10-2]. There are also C-H?? and weak ?-? inter-actions present [centroid-centroid distance = 3.990?(2)?Å, plane-plane distance = 3.6352?(15)?Å and ring slippage = 1.644?Å], forming of a three-dimensional structure.

SUBMITTER: Davis WL

PROVIDER: S-EPMC3588800 | biostudies-other | 2012 Dec

REPOSITORIES: biostudies-other

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trans-Di-μ-chlorido-bis-{chlorido[tris-(3,5-dimethyl-phen-yl)phosphane-κP]palla-dium(II)} dichloro-methane monosolvate.

Davis Wade L WL Muller Alfred A

Acta crystallographica. Section E, Structure reports online 20121130 Pt 12

In the dimeric title compound, [Pd2Cl4{P(C8H9)3}2]·CH2Cl2, the metal complex molecule is situated about an inversion centre and is accompanied by a dichloro-methane solvent mol-ecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris-(3,5-dimethyl-phen-yl)phos-phane ligand was calculated to be 169°. In the crystal, the metal complex and solvent mol-ecules are linked via C-H⋯Cl inter-actions, gener ...[more]

PMID: 23468765

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