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Tris(1,10-phenanthroline-?(2) N,N')ruthenium(II) bis-(perchlorate).

ABSTRACT: The asymmetric unit of the title compound, [Ru(C12H8N2)3](ClO4)2, contains one octahedrally coordinated Ru(II) cation of the ruthenium-phenanthroline complex and three differently occupied perchlorate anions: two, denoted A and B, are located on the twofold axis while another, denoted C, is positioned in the proximity of the twofold screw axis. Perchlorate anions B and C are severely disordered. The occupancies of the two major conformers of anion B refined to 0.302?(6) and 0.198?(6). Perchlorate ion C was modeled in two alternate conformations which refined to occupancies of 0.552?(10) and 0.448?(10).

SUBMITTER: Kozlowska M

PROVIDER: S-EPMC3588804 | biostudies-other | 2012 Dec

REPOSITORIES: biostudies-other

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Tris(1,10-phenanthroline-κ(2) N,N')ruthenium(II) bis-(perchlorate).

Kozlowska Mariana M Rodziewicz Pawel P Brus Diana Malgorzata DM Czyrko Justyna J Brzezinski Krzysztof K

Acta crystallographica. Section E, Structure reports online 20121130 Pt 12

The asymmetric unit of the title compound, [Ru(C12H8N2)3](ClO4)2, contains one octahedrally coordinated Ru(II) cation of the ruthenium-phenanthroline complex and three differently occupied perchlorate anions: two, denoted A and B, are located on the twofold axis while another, denoted C, is positioned in the proximity of the twofold screw axis. Perchlorate anions B and C are severely disordered. The occupancies of the two major conformers of anion B refined to 0.302 (6) and 0.198 (6). Perchlorat ...[more]

PMID: 23468769

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