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Cis,cis,cis-(Acetato-?(2) O,O')bis-[1,2-bis-(diphenyl-phosphan-yl)ethane-?(2) P,P']ruthenium(II) 0.75-trifluoro-methane-sulfonate 0.25-chloride.

ABSTRACT: In the title Ru(II) carboxyl-ate compound, [Ru(C2H3O2)(C26H24P2)2](CF3O3S)0.75Cl0.25, the distorted tris-bidentate octa-hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis-(diphenyl-phosphan-yl)ethane ligands [Ru-P = 2.2881?(13)-2.3791?(13)?Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191?(3) and 2.202?(3)?Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoro-methane-sulfonate anions and one chloride anion, with two such formula units in the unit cell.

SUBMITTER: Figueira J

PROVIDER: S-EPMC3629500 | biostudies-other | 2013 Apr

REPOSITORIES: biostudies-other

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cis,cis,cis-(Acetato-κ(2) O,O')bis-[1,2-bis-(diphenyl-phosphan-yl)ethane-κ(2) P,P']ruthenium(II) 0.75-trifluoro-methane-sulfonate 0.25-chloride.

Figueira João J Rodrigues João J Rodrigues João J Valkonen Arto A

Acta crystallographica. Section E, Structure reports online 20130323 Pt 4

In the title Ru(II) carboxyl-ate compound, [Ru(C2H3O2)(C26H24P2)2](CF3O3S)0.75Cl0.25, the distorted tris-bidentate octa-hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis-(diphenyl-phosphan-yl)ethane ligands [Ru-P = 2.2881 (13)-2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula ...[more]

PMID: 23634018

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