Unknown

Dataset Information

0

Tetra-aceto-nitrile-lithium tetra-iso-thio-cyanato-borate.


ABSTRACT: The crystal structure of the title salt, [Li(CH3CN)4][B(NCS)4], is composed of discrete cations and anions. Both the Li and B atoms show a tetra-hedral coordination by four equal ligands. The aceto-nitrile and iso-thio-cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra-hedral value [108.92?(18)-109.94?(16)°], but the bond angles at the Li atom show larger deviations [106.15?(17)-113.70?(17)°].

SUBMITTER: Breunig JM 

PROVIDER: S-EPMC3647800 | biostudies-other | 2013 May

REPOSITORIES: biostudies-other

altmetric image

Publications

Tetra-aceto-nitrile-lithium tetra-iso-thio-cyanato-borate.

Breunig Jens Michael JM   Wietelmann Ulrich U   Lerner Hans-Wolfram HW   Bolte Michael M  

Acta crystallographica. Section E, Structure reports online 20130410 Pt 5


The crystal structure of the title salt, [Li(CH3CN)4][B(NCS)4], is composed of discrete cations and anions. Both the Li and B atoms show a tetra-hedral coordination by four equal ligands. The aceto-nitrile and iso-thio-cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra-hedral value [108.92 (18)-109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)-113.70 (17)°]. ...[more]

Similar Datasets

| S-EPMC3772428 | biostudies-literature
| S-EPMC6829719 | biostudies-literature
| S-EPMC3998454 | biostudies-literature
| S-EPMC3998583 | biostudies-literature
| S-EPMC6895946 | biostudies-literature
| S-EPMC3790353 | biostudies-literature
| S-EPMC2969749 | biostudies-literature
| S-EPMC9462146 | biostudies-literature
| S-EPMC3212116 | biostudies-other
| S-EPMC10833408 | biostudies-literature