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ABSTRACT:
SUBMITTER: Breunig JM
PROVIDER: S-EPMC3647800 | biostudies-other | 2013 May
REPOSITORIES: biostudies-other
Breunig Jens Michael JM Wietelmann Ulrich U Lerner Hans-Wolfram HW Bolte Michael M
Acta crystallographica. Section E, Structure reports online 20130410 Pt 5
The crystal structure of the title salt, [Li(CH3CN)4][B(NCS)4], is composed of discrete cations and anions. Both the Li and B atoms show a tetra-hedral coordination by four equal ligands. The aceto-nitrile and iso-thio-cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra-hedral value [108.92 (18)-109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)-113.70 (17)°]. ...[more]