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Aqua-bis-(4-methyl-benzene-sulfonato-?O)(?(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III) monohydrate.

ABSTRACT: The title half-sandwich rhodium(III) complex, [Rh(C10H15)(C7H7O3S)2(H2O)]·H2O, consists of a ?-bonded penta-methyl-cyclo-penta-dienyl group, two ?-bonded tosyl-ate groups and an aqua ligand. The structure displays both inter- and intra-molecular O-H?O hydrogen bonding. The inter-molecular hydrogen bonding results in an extended helical chain along a 21 screw axis parallel to c, due to hydrogen bonding from the coordinating water ligand to the lattice water mol-ecule and then to a sulfonate O atom of a different asymmetric unit.

SUBMITTER: Roy CP

PROVIDER: S-EPMC3647804 | biostudies-other | 2013 May

REPOSITORIES: biostudies-other

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Aqua-bis-(4-methyl-benzene-sulfonato-κO)(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III) monohydrate.

Roy Christopher P CP Boyer Pauline M PM Merola Joseph S JS

Acta crystallographica. Section E, Structure reports online 20130413 Pt 5

The title half-sandwich rhodium(III) complex, [Rh(C10H15)(C7H7O3S)2(H2O)]·H2O, consists of a π-bonded penta-methyl-cyclo-penta-dienyl group, two σ-bonded tosyl-ate groups and an aqua ligand. The structure displays both inter- and intra-molecular O-H⋯O hydrogen bonding. The inter-molecular hydrogen bonding results in an extended helical chain along a 21 screw axis parallel to c, due to hydrogen bonding from the coordinating water ligand to the lattice water mol-ecule and then to a sulfonate O ato ...[more]

PMID: 23723770

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