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Catena-Poly[[bis-(2-meth-oxy-aniline-?N)cadmium]-di-?-thio-cyanato-?(2) N:S;?(2) S:N].

ABSTRACT: The structure of the title compound, [Cd(NCS)2(C7H9NO)2] n , consists of cadmium-thio-cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging ?-NCS-N:S thio-cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa-hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth-oxy-aniline ligands. The crystal structure is stabilized by intra-layer N-H?S hydrogen bonds.

SUBMITTER: Chemli R 

PROVIDER: S-EPMC3647823 | biostudies-other | 2013 May

REPOSITORIES: biostudies-other

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catena-Poly[[bis-(2-meth-oxy-aniline-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

Chemli Rakia R   Kamoun Slaheddine S   Roisnel Thierry T  

Acta crystallographica. Section E, Structure reports online 20130427 Pt 5

The structure of the title compound, [Cd(NCS)2(C7H9NO)2] n , consists of cadmium-thio-cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio-cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa-hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth-oxy-aniline ligands. The crystal structure is stabilized by intra-layer N-H⋯S hydrogen bonds. ...[more]

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