Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N-[(E)-4-Bromo-benzyl-idene]-3,4-di-methyl-aniline.

ABSTRACT: In the title compound, C15H14BrN, the dihedral angle between the benzene rings is 6.4?(2)° and the mol-ecule has an E conformation about the C=N bond. In the crystal, mol-ecules are linked by C-H?? inter-actions, forming two-dimensional networks lying parallel to (001).

SUBMITTER: Sun LX

PROVIDER: S-EPMC3647832 | biostudies-other | 2013 May

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

N-[(E)-4-Bromo-benzyl-idene]-3,4-di-methyl-aniline.

Sun Li-Xia LX Zhu Ling-Zhi LZ Wang Jun-Kai JK

Acta crystallographica. Section E, Structure reports online 20130405 Pt 5

In the title compound, C15H14BrN, the dihedral angle between the benzene rings is 6.4 (2)° and the mol-ecule has an E conformation about the C=N bond. In the crystal, mol-ecules are linked by C-H⋯π inter-actions, forming two-dimensional networks lying parallel to (001). ...[more]

PMID: 23723798

Similar Datasets

N-[(E)-4-Fluoro-benzyl-idene]-3,4-di-methyl-aniline.

Project description:In the title Schiff base, C(15)H(14)FN, the N=C bond length of 1.263?(2)?Å is shorter than the N-C bond [1.426?(2)?Å], indicating a typical imine double bond. Moreover, the C-N-C angle is 118.5?(2)°. The benzene rings form a dihedral angle of 51.22?(5)°.

| S-EPMC3414334 | biostudies-literature

N-[(E)-4-Bromo-benzyl-idene]-2,3-di-methyl-aniline.

Project description:The title compound, C15H14BrN, has an E conformation about the C=N bond and the dihedral angle between the benzene rings is 50.7?(2)°. In the crystal, mol-ecules are linked via C-H?? inter-actions, forming columns propagating along [010].

| S-EPMC3647831 | biostudies-other

N-[4-(Di-methyl-amino)-benzyl-idene]-4-methyl-aniline.

Project description:The mol-ecules of the title compound, C16H18N2, exists in a trans conformation with respect to the C=N bond [1.270 (3) Å]. The least-squares plane of the di-methyl-amino group makes a dihedral angle of 1.3 (2)° with the ring to which it is attached. The dihedral angle between the two aromatic rings is 11.70 (2)°. The crystal structure features weak C-H⋯π inter-actions.

| S-EPMC3685060 | biostudies-literature

4,6-Di-bromo-N-{3-[(4,6-di-bromo-2,3-di-methyl-phenyl)imino]butan-2-yl-idene}-2,3-di-methyl-aniline.

Project description:The title compound, C20H20Br4N2, is a product of the condensation reaction of 4,6-di-bromo-2,3-di-methyl-aniline and butane-2,3-dione. The mol-ecule has a center of symmetry at the mid-point of the central C-C bond. The dihedral angle between the benzene ring and the 1,4-di-aza-butadiene plane is 78.3?(2)°. Niether hydrogen bonding nor aromatic stacking is observed in the crystal structure.

| S-EPMC3790371 | biostudies-literature

N'-(5-Bromo-2-methoxy-benzyl-idene)-3,4-methyl-enedioxy-benzohydrazide.

Project description:In the title mol-ecule, C(16)H(13)BrN(2)O(4), the two benzene rings form a dihedral angle of 74.9?(2)°. In the crystal, mol-ecules are linked via inter-molecular N-H?O hydrogen bonds into chains propagating along the c axis.

| S-EPMC2969257 | biostudies-literature

2-[(3,4-Di-chloro-benzyl-idene)amino]-4-methyl-phenol.

Project description:In the title compound, C14H11Cl2NO, the dihedral angle between the benzene rings is 15.36 (8)°. A phenol-imine-type intra-molecular O-H⋯N hydrogen bond generates an S(5) ring motif. In the crystal, a pair of weak C-H⋯O hydrogen bonds form an R 2 (1)(7) ring motif involving glide-plane-related mol-ecules. The mol-ecules linked via these inter-actions form chains along [101].

| S-EPMC3685100 | biostudies-literature

2,6-Di-bromo-4-methyl-aniline.

Project description:In the title compound, C7H7Br2N, the C-C-C bond angles of the benzene ring are notably distorted and two short intamolecular N-H⋯Br contacts occur. In the crystal, the mol-ecules are linked by N-H⋯N hydrogen bonds to generate C(2) chains propagating in the [100] direction.

| S-EPMC9462035 | biostudies-literature

4-Bromo-N-(3,4,5-trimethoxy-benzyl-idene)aniline.

Project description:The title compound, C(16)H(16)BrNO(3), adopts an E configuration with respect to the imine C=N bond. The two benzene rings are twisted with respect to each other at an angle of 38.3?(1)°. In the crystal structure, mol-ecules are connected by weak bifurcated C-H?(O, O) hydrogen bonds, forming a helical chain along the b axis.

| S-EPMC2968382 | biostudies-literature

3,4-Dimeth-oxy-N-(4-nitro-benzyl-idene)-aniline.

Project description:In the title mol-ecule, C(15)H(14)N(2)O(4), the dihedral angle between the two benzene rings is 29.52 (8)°. The nitro and two meth-oxy substituents are almost coplanar with their respective benzene rings. The crystal structure is stabilized by inter-molecular C-H⋯O inter-actions.

| S-EPMC2959688 | biostudies-literature

3,4-Dimeth-oxy-N-(3-nitro-benzyl-idene)aniline.

Project description:The title compound, C(15)H(14)N(2)O(4), has two crystallographically independent mol-ecules in the asymmetric unit. In both mol-ecules, the nitro and the two meth-oxy substituents are coplanar with the benzene rings to which they are attached. The benzene rings are nearly coplanar, with dihedral angles between the two benzene rings of 10.39 (8) and 5.95 (8)° in the two mol-ecules. The two independent mol-ecules in the asymmetric unit are rotated with respect to each other such that the dihedral angles between equivalent benzene rings are 49.11 (8) and 63.93 (8)°. In the crystal structure, inter-molecular C-H⋯O hydrogen-bond contacts and a weak C-H⋯π inter-action are observed.

| S-EPMC2959659 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data