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(O-Methyl di-thio-carbonato-?S)tri-phenyl-tin(IV).

ABSTRACT: In the title compound, [Sn(C6H5)3(C2H3OS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry. A short Sn?O contact [2.988?(4)?Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550?(8):0.450?(8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57?(18):0.43?(18).

SUBMITTER: Javed F

PROVIDER: S-EPMC3684880 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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(O-Methyl di-thio-carbonato-κS)tri-phenyl-tin(IV).

Javed Fatima F Ali Saqib S Shah Wajid W Tahir M Nawaz MN Ullah Hameed H

Acta crystallographica. Section E, Structure reports online 20130515 Pt 6

In the title compound, [Sn(C6H5)3(C2H3OS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18). ...[more]

PMID: 23794982

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Crystal structures of di-aquadi-μ-hydroxido-tris-[tri-methyl-tin(IV)] diformatotri-methyl-stannate(IV) and di-μ-hydroxido-tris-[tri-methyl-tin(IV)] chloride monohydrate.

Project description:The title compounds, [Sn3(CH3)9(OH)2(H2O)2][Sn(CH3)3(CHO2)2] (1) and [Sn3(CH3)9(OH)2]Cl·H2O (2), are partially condensed products of hydrolysed tri-methyl-tin chloride. In the structures of 1 and 2, short cationic tris-tannatoxanes (C9H29O2Sn3) are bridged by a diformatotri-methyl-tin anion or a chloride anion, respectively. Hydrogen bridges are present and supposedly stabilize these structures against further polymerization to the known polymeric tri-methyl-tin hydroxide. Especially noteworthy is that the formate present in this structure was formed from atmospheric CO2.

| S-EPMC5050785 | biostudies-literature

[4-(Dimethyl-amino)-pyridine-?N(1)]tri-methyl(thio-cyanato-?N)tin(IV).

Project description:In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033?(4)?Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8?(2)%.

| S-EPMC3379119 | biostudies-literature

(2-Methyl-quinolin-8-olato-?N,O)di-phenyl-(thio-cyanato-?N)tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(10)H(8)NO)(NCS)], is chelated by the 2-methyl-quinolin-8-olate anion and is five-coordinate in a trigonal-bipramidal geometry [C-Sn-C = 133.47?(13) and 138.77?(12)°]. There are two independent mol-ecules of similar conformation in the asymmetric unit.

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Crystal structures and Hirshfeld surface analyses of bis-[N,N-bis-(2-meth-oxy-eth-yl)di-thio-carbamato-?2S,S']di-n-butyl-tin(IV) and [N-(2-meth-oxy-eth-yl)-N-methyl-dithio-carbamato-?2S,S']tri-phenyl-tin(IV).

Project description:The crystal and mol-ecular structures of the two title organotin di-thio-carbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound di-thio-carbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the metal atom in (I) and a distorted tetra-hedral geometry in (II). The complete mol-ecule of (I) is generated by a crystallographic twofold axis (Sn site symmetry 2). In the crystal of (I), mol-ecules self-assemble into a supra-molecular array parallel to (10-1) via methyl-ene-C-H?O(meth-oxy) inter-actions. In the crystal of (II), supra-molecular dimers are formed via pairs of weak phenyl-C-H??(phen-yl) contacts. In each of (I) and (II), the specified assemblies connect into a three-dimensional architecture without directional inter-actions between them. Hirshfeld surface analyses confirm the importance of H?H contacts in the mol-ecular packing of each of (I) and (II), and in the case of (I), highlight the importance of short meth-oxy-H?H(but-yl) contacts between layers.

| S-EPMC5947791 | biostudies-literature

[N-Benzyl-N-(2-phenyl-eth-yl)di-thio-carbamato-κ2S,S']tri-phenyl-tin(IV) and [bis-(2-meth-oxy-eth-yl)di-thio-carbamato-κ2S,S']tri-phenyl-tin(IV): crystal structures and Hirshfeld surface analysis.

Project description:The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the di-thio-carbamate ligand coordinates the SnIV atom in an asymmetric manner, leading to a highly distorted trigonal-bipyramidal coordination geometry defined by a C3S2 donor set with the weakly bound S atom approximately trans to one of the ipso-C atoms. A similar structure is found in (II), but the di-thio-carbamate ligand coordinates in an even more asymmetric fashion. The packing in (I) features supra-molecular chains along the c axis sustained by C-H⋯π inter-actions; chains pack with no directional inter-actions between them. In (II), supra-molecular layers are formed, similarly sustained by C-H⋯π inter-actions; these stack along the b axis. An analysis of the Hirshfeld surfaces for (I) and (II) confirms the presence of the C-H⋯π inter-actions but also reveals the overall dominance of H⋯H contacts in the respective crystals.

| S-EPMC5050781 | biostudies-literature

Di-chlorido-diphenyl-bis-(thio-urea-?S)tin(IV).

Project description:The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 environment. Individual mol-ecules are connected through N-H?Cl hydrogen bonds, leading to a three-dimensional network structure. Intra-molecular N-H?Cl hydrogen bonds are also present.

| S-EPMC3790350 | biostudies-literature

Di-chlorido-dimethyl-bis-(thio-urea-κS)tin(IV).

Project description:The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-mol-ecules in the asymmetric unit. Both mol-ecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octa-hedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thio-urea S atoms. In the crystal, mol-ecules are linked via N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional structure.

| S-EPMC3998430 | biostudies-literature

catena-Poly[[tri-n-butyl-tin(IV)]-?-2-thio-phene-acetato].

Project description:The title compound, [Sn(C(4)H(9))(3)(C(6)H(5)O(2)S)](n), possesses an infinite chain structure. The SnO(2)C(3) centre has a distorted trigonal-bipyramidal geometry (? = 0.145) with the O atoms in the axial positions. Atoms of the thio-phene group S1 and C4 are disordered over two sites The S atom and one C atom, with attached H atom, of the thiophene ring are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

| S-EPMC2919292 | biostudies-literature

(3-Anilino-1-phenyl-imino-thio-ureato)chloridodimethyl-tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(13)H(11)N(4)S)Cl], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal geometry, with two methyl groups and one S atom in the equatorial plane, and one N atom and the Cl atom occupying the apical positions.

| S-EPMC2969056 | biostudies-literature

Di-?-hydroxido-bis-[dimeth-yl(thio-cyanato-?N)tin(IV)].

Project description:The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H?S and C-H? S hydrogen-bonding inter-actions into a three-dimensional network.

| S-EPMC3588706 | biostudies-literature

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