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(Adipato-?(2) O,O')di-aqua-[bis-(pyridin-2-yl-?N)amine]-cobalt(II) trihydrate.

ABSTRACT: In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octa-hedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate di-pyridyldi-amine ligand, two O-atom donors from one of the carboxyl-ate groups of the bidentate chelating adipate ligand and two water mol-ecules. In addition, there are three solvent water mol-ecules which are involved in both intra- and inter-unit O-H?O hydrogen-bonding inter-actions, which together with an amine-water N-H?O hydrogen bond produce a three-dimensional framework.

SUBMITTER: Setifi Z

PROVIDER: S-EPMC3684895 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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(Adipato-κ(2) O,O')di-aqua-[bis-(pyridin-2-yl-κN)amine]-cobalt(II) trihydrate.

Setifi Zouaoui Z Setifi Fatima F Smith Graham G El-Ghozzi Malika M Rouag Djamil-Azzeddine DA Avignant Daniel D Merazig Hocine H

Acta crystallographica. Section E, Structure reports online 20130522 Pt 6

In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octa-hedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate di-pyridyldi-amine ligand, two O-atom donors from one of the carboxyl-ate groups of the bidentate chelating adipate ligand and two water mol-ecules. In addition, there are three solvent water mol-ecules which are involved in both intra- and inter-unit O-H⋯O hydrogen-bonding inter-actions, which together with an amine-water N-H⋯ ...[more]

PMID: 23794997

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