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1,6-Di-bromo-naphthalen-2-ol methanol monosolvate.

ABSTRACT: The naphthol-containing mol-ecule of the title compound, C10H6Br2O·CH3OH, crystallized as a methanol monosolvate and is planar to within 0.069?(1)?Å for all non-H atoms. In the crystal, mol-ecules are linked by two pairs of O-H?O hydrogen bonds, involving the methanol mol-ecule, forming dimer-like arrangements. The crystal structure is further stabilized by ?-? stacking [centroid-centroid distance = 3.676?(2)?Å] and Br?Br inter-actions [3.480?(4) and 3.786?(1)?Å], forming a three-dimensional structure.

SUBMITTER: Sanders MB

PROVIDER: S-EPMC3770412 | biostudies-other | 2013

REPOSITORIES: biostudies-other

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1,6-Di-bromo-naphthalen-2-ol methanol monosolvate.

Sanders Marisa B MB Furkan Tania T Leonard Emily E Chan Benny C BC

Acta crystallographica. Section E, Structure reports online 20130626 Pt 7

The naphthol-containing mol-ecule of the title compound, C10H6Br2O·CH3OH, crystallized as a methanol monosolvate and is planar to within 0.069 (1) Å for all non-H atoms. In the crystal, mol-ecules are linked by two pairs of O-H⋯O hydrogen bonds, involving the methanol mol-ecule, forming dimer-like arrangements. The crystal structure is further stabilized by π-π stacking [centroid-centroid distance = 3.676 (2) Å] and Br⋯Br inter-actions [3.480 (4) and 3.786 (1) Å], forming a three-dimensional str ...[more]

PMID: 24046697

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