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An efficient and cost-effective preparation of di-O-acetyl-D-rhamnal.


ABSTRACT: We have developed a synthetic route to the frequently utilized deoxysugar building block di-O-acetyl-D-rhamnal originating from the inexpensive starting material methyl ?-D-glucopyranoside. Our approach proceeds in five steps with minimal column chromatography purification needed to afford the title compound in good overall yield. 2009 Elsevier Ltd. All rights reserved.

SUBMITTER: Miller JN 

PROVIDER: S-EPMC3781929 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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An efficient and cost-effective preparation of di-<i>O</i>-acetyl-D-rhamnal.

Miller Justin N JN   Pongdee Rongson R  

Tetrahedron letters 20130601 24


We have developed a synthetic route to the frequently utilized deoxysugar building block di-<i>O</i>-acetyl-D-rhamnal originating from the inexpensive starting material methyl α-D-glucopyranoside. Our approach proceeds in five steps with minimal column chromatography purification needed to afford the title compound in good overall yield. 2009 Elsevier Ltd. All rights reserved. ...[more]

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