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2-[4-(2-Chloro-acet-yl)phen-yl]-2-methyl-1-(pyrrolidin-1-yl)propan-1-one.

ABSTRACT: The asymmetric unit of the title compound, C16H20ClNO2, contains two mol-ecules in which the dihedral angles between the benzene ring and the plane of the amide unit are 77.4?(1) and 81.1?(1)°. In both mol-ecules, the five-membered ring adopts an envelope conformation with one of the ?-C atoms as the flap. In the crystal, mol-ecules are connected via C-H?O hydrogen bonds, forming chains along the b-axis direction. These chains are further linked by C-H?? inter-actions, forming a three-dimensional network.

SUBMITTER: Ren DM

PROVIDER: S-EPMC3793811 | biostudies-other | 2013

REPOSITORIES: biostudies-other

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2-[4-(2-Chloro-acet-yl)phen-yl]-2-methyl-1-(pyrrolidin-1-yl)propan-1-one.

Ren Dong-Mei DM

Acta crystallographica. Section E, Structure reports online 20130727 Pt 8

The asymmetric unit of the title compound, C16H20ClNO2, contains two mol-ecules in which the dihedral angles between the benzene ring and the plane of the amide unit are 77.4 (1) and 81.1 (1)°. In both mol-ecules, the five-membered ring adopts an envelope conformation with one of the β-C atoms as the flap. In the crystal, mol-ecules are connected via C-H⋯O hydrogen bonds, forming chains along the b-axis direction. These chains are further linked by C-H⋯π inter-actions, forming a three-dimensiona ...[more]

PMID: 24109398

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