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Bruceolline J: 2-hy-droxy-3,3-dimethyl-2,3-di-hydro-cyclo-penta-[b]indol-1(4H)-one.

ABSTRACT: The 12-membered cyclo-penta-[b]indole ring system in the title compound, C13H13NO2, deviates only slightly from planarity (r.m.s. deviation = 0.051?Å). In the crystal, N-H?O and O-H?O hydrogen bonds link the mol-ecules into sheets parallel to (100). The five-membered cyclopentanone ring is in slightly distorted envelope conformation with the C atom bearing the hydroxy substituent as the flap.

SUBMITTER: Lopchuk JM

PROVIDER: S-EPMC3793830 | biostudies-other | 2013

REPOSITORIES: biostudies-other

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Bruceolline J: 2-hy-droxy-3,3-dimethyl-2,3-di-hydro-cyclo-penta-[b]indol-1(4H)-one.

Lopchuk Justin M JM Gribble Gordon W GW Millikan Sean P SP Jasinski Jerry P JP

Acta crystallographica. Section E, Structure reports online 20130731 Pt 8

The 12-membered cyclo-penta-[b]indole ring system in the title compound, C13H13NO2, deviates only slightly from planarity (r.m.s. deviation = 0.051 Å). In the crystal, N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules into sheets parallel to (100). The five-membered cyclopentanone ring is in slightly distorted envelope conformation with the C atom bearing the hydroxy substituent as the flap. ...[more]

PMID: 24109417

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