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Bis[(di-methyl-phosphor-yl)methan-amin-ium] tetra-chlorido-palladate(II).

ABSTRACT: In the crystal structure of the title compound, (C3H11NOP)2[PdCl4], (di-methyl-phosphor-yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N-H?O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl4](2-) counter-dianion is located about a center of inversion. The dications and the [PdCl4](2-) dianions are connected by medium-strong N-H?Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N-H?Cl hydrogen bonds connect the chains into a three-dimensional network.

SUBMITTER: Reiss GJ

PROVIDER: S-EPMC3884266 | biostudies-other | 2013 Oct

REPOSITORIES: biostudies-other

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Bis[(di-methyl-phosphor-yl)methan-amin-ium] tetra-chlorido-palladate(II).

Reiss Guido J GJ

Acta crystallographica. Section E, Structure reports online 20131019 Pt 11

In the crystal structure of the title compound, (C3H11NOP)2[PdCl4], (di-methyl-phosphor-yl)methanaminium (dpmaH(+)) cations are connected head-to-tail by strong N-H⋯O hydrogen bonds, forming inversion-related cyclic dimers. The square-planar [PdCl4](2-) counter-dianion is located about a center of inversion. The dications and the [PdCl4](2-) dianions are connected by medium-strong N-H⋯Cl hydrogen bonds, forming zigzag chains parallel to [001]. Somewhat weaker N-H⋯Cl hydrogen bonds connect the ch ...[more]

PMID: 24454042

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