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Lacinilene C 7-methyl ether.

ABSTRACT: The title compound, C16H20O3 [systematic name: 1-hy-droxy-7-meth-oxy-1,6-dimethyl-4-(propan-2-yl)naphthalen-2(1H)-one], is a sesquiterpene isolated from foliar tissues of the cotton plant and is of inter-est with respect to its anti-bacterial properties. Its phenyl ring is ideally planar, and the maximum of deviation in the second ring is 0.386?(3)?Å. The hy-droxy group and the methyl group are oriented in an equatorial fashion and axial, respectively, to the second ring. In the crystal, inversion dimers are formed through pairs of O-H?O hydrogen bonds. Weak C-H?O hydrogen bonds link the dimers into columns along the c axis. These columns form a crystal structure with a crystal packing factor of 0.66.

SUBMITTER: Uzbekov VV

PROVIDER: S-EPMC3884496 | biostudies-other | 2013

REPOSITORIES: biostudies-other

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Lacinilene C 7-methyl ether.

Uzbekov Vyacheslav V VV Talipov Samat A SA Ibragimov Bakhtiyar T BT Stipanovic Robert D RD Bell Alois A AA

Acta crystallographica. Section E, Structure reports online 20130807 Pt 9

The title compound, C16H20O3 [systematic name: 1-hy-droxy-7-meth-oxy-1,6-dimethyl-4-(propan-2-yl)naphthalen-2(1H)-one], is a sesquiterpene isolated from foliar tissues of the cotton plant and is of inter-est with respect to its anti-bacterial properties. Its phenyl ring is ideally planar, and the maximum of deviation in the second ring is 0.386 (3) Å. The hy-droxy group and the methyl group are oriented in an equatorial fashion and axial, respectively, to the second ring. In the crystal, inversi ...[more]

PMID: 24427033

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