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Rac-2-Phenyl-1-[(2,4,6-triiso-propyl-benzene)-sulfon-yl]aziridine.

ABSTRACT: In the title compound, C23H31NO2S, the geometry of the triiso-propyl-phenyl group is slightly distorted, with elongated C-C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228?(2)?Å. This distortion is caused by the bulky substituents and, in comparison, an unbent geometry is observed in N-toluene-sulfonyl-aziridine [Zhu et al. (2006 ?). Acta Cryst. E62, o1507-o1508]. ?-? inter-actions between adjacent benzene rings [centroid-centroid distance = 3.7928?(11)?Å] and are observed.

SUBMITTER: Golz C

PROVIDER: S-EPMC3998314 | biostudies-other | 2014 Feb

REPOSITORIES: biostudies-other

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rac-2-Phenyl-1-[(2,4,6-triiso-propyl-benzene)-sulfon-yl]aziridine.

Golz Christopher C Preut Hans H Strohmann Carsten C

Acta crystallographica. Section E, Structure reports online 20140115 Pt 2

In the title compound, C23H31NO2S, the geometry of the triiso-propyl-phenyl group is slightly distorted, with elongated C-C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) Å. This distortion is caused by the bulky substituents and, in comparison, an unbent geometry is observed in N-toluene-sulfonyl-aziridine [Zhu et al. (2006 ▶). Acta Cryst. E62, o1507-o1508]. π-π inter-actions between adjacent benzene rings [centroid-centroid distance = 3.7928 (11 ...[more]

PMID: 24764875

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Crystal structure of 1-[(2,4,6-triiso-propyl-phen-yl)sulfon-yl]aziridine.

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Crystal structure of [2-(tri-ethyl-ammonio)-eth-yl][(2,4,6-triiso-propyl-phen-yl)sulfon-yl]amide tetra-hydrate.

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