Unknown

Dataset Information

0

Di-chlorido-dimethyl-bis-(thio-urea-?S)tin(IV).

ABSTRACT: The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-mol-ecules in the asymmetric unit. Both mol-ecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octa-hedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thio-urea S atoms. In the crystal, mol-ecules are linked via N-H?Cl and N-H?S hydrogen bonds, forming a three-dimensional structure.

SUBMITTER: Sow Y 

PROVIDER: S-EPMC3998430 | biostudies-other | 2014 Mar

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Di-chlorido-dimethyl-bis-(thio-urea-κS)tin(IV).

Sow Yaya Y   Diop Libasse L   Fernandes Manuel A MA   Stoeckli-Evans Helen H  

Acta crystallographica. Section E, Structure reports online 20140208 Pt 3

The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-mol-ecules in the asymmetric unit. Both mol-ecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octa-hedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thio-urea S atoms. In the crystal, mol-ecules are linked via N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional structure. ...[more]