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{2-[(2-Hy-droxy-benzyl-idene)amino]-4,5,6,7-tetra-hydro-1-benzo-thio-phen-3-yl}(phen-yl)methanone.

ABSTRACT: In the title compound, C22H19NO2S, the cyclo-hexene ring adopts a slightly distorted half-chair conformation. The dihedral angles between the mean planes of the thio-phene ring and the phenyl and 2-hy-droxy-phenyl rings are 70.4?(5) and 12.1?(9)°, respectively. The phenyl and 2-hy-droxy-phenyl rings are twisted with respect to one another by 81.0?(6)°. A short intra-molecular O-H?N hydrogen bond is observed. In the crystal, weak C-H?O inter-actions link the mol-ecules into zigzag chains diagonally along [100] .

SUBMITTER: Kaur M

PROVIDER: S-EPMC3998550 | biostudies-other | 2014 Apr

REPOSITORIES: biostudies-other

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{2-[(2-Hy-droxy-benzyl-idene)amino]-4,5,6,7-tetra-hydro-1-benzo-thio-phen-3-yl}(phen-yl)methanone.

Kaur Manpreet M Jasinski Jerry P JP Kavitha Channappa N CN Yathirajan H S HS Byrappa K K

Acta crystallographica. Section E, Structure reports online 20140326 Pt 4

In the title compound, C22H19NO2S, the cyclo-hexene ring adopts a slightly distorted half-chair conformation. The dihedral angles between the mean planes of the thio-phene ring and the phenyl and 2-hy-droxy-phenyl rings are 70.4 (5) and 12.1 (9)°, respectively. The phenyl and 2-hy-droxy-phenyl rings are twisted with respect to one another by 81.0 (6)°. A short intra-molecular O-H⋯N hydrogen bond is observed. In the crystal, weak C-H⋯O inter-actions link the mol-ecules into zigzag chains diagonal ...[more]

PMID: 24826172

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[2-(Benzyl-idene-amino)-4,5,6,7-tetra-hydro-benzo[b]thio-phen-3-yl](phen-yl)methanone.

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