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Visible-light photoredox catalysis enabled bromination of phenols and alkenes.

ABSTRACT: A mild and efficient methodology for the bromination of phenols and alkenes has been developed utilizing visible light-induced photoredox catalysis. The bromine was generated in situ from the oxidation of Br(-) by Ru(bpy)3 (3+), both of which resulted from the oxidative quenching process.

SUBMITTER: Zhao Y

PROVIDER: S-EPMC3999835 | biostudies-other | 2014

REPOSITORIES: biostudies-other

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Visible-light photoredox catalysis enabled bromination of phenols and alkenes.

Zhao Yating Y Li Zhe Z Yang Chao C Lin Run R Xia Wujiong W

Beilstein journal of organic chemistry 20140307

A mild and efficient methodology for the bromination of phenols and alkenes has been developed utilizing visible light-induced photoredox catalysis. The bromine was generated in situ from the oxidation of Br(-) by Ru(bpy)3 (3+), both of which resulted from the oxidative quenching process. ...[more]

PMID: 24778712

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