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Poly[(?3-3,5-diisopropyl-4H-1,2,4-triazolato-?(3) N:N':N'')silver(I)].

ABSTRACT: In the polymeric title compound, [Ag(C8H14N3)] n , the Ag(I) cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The Ag(I) cation deviates from the coordination plane by 0.014?(1)?Å and the N-Ag-N bond angles are 96.85?(11), 97.72?(10) and 165.39?(12)°. The triazolate anion bridges three Ag(I) cations, forming a three-dimensional polymeric network.

SUBMITTER: Cui GG

PROVIDER: S-EPMC4011292 | biostudies-other | 2014 May

REPOSITORIES: biostudies-other

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Poly[(μ3-3,5-diisopropyl-4H-1,2,4-triazolato-κ(3) N:N':N'')silver(I)].

Cui Guo-Gen GG Yang Xiao-Xi XX Yang Jian-Ping JP Jiang Xiang X

Acta crystallographica. Section E, Structure reports online 20140426 Pt 5

In the polymeric title compound, [Ag(C8H14N3)] n , the Ag(I) cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The Ag(I) cation deviates from the coordination plane by 0.014 (1) Å and the N-Ag-N bond angles are 96.85 (11), 97.72 (10) and 165.39 (12)°. The triazolate anion bridges three Ag(I) cations, forming a three-dimensional polymeric network. ...[more]

PMID: 24860318

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