Ontology highlight
ABSTRACT:
SUBMITTER: Peric I
PROVIDER: S-EPMC4076007 | biostudies-other | 2014 Jun
REPOSITORIES: biostudies-other
The journal of physical chemistry. B 20140613 25
Bimolecular collision rate constants of a model solute are measured in water at T = 259-303 K, a range encompassing both normal and supercooled water. A stable, spherical nitroxide spin probe, perdeuterated 2,2,6,6-tetramethyl-4-oxopiperidine-1-oxyl, is studied using electron paramagnetic resonance spectroscopy (EPR), taking advantage of the fact that the rotational correlation time, τ(R), the mean time between successive spin exchanges within a cage, τ(RE), and the long-time-averaged spin excha ...[more]