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Tetra-ammineplatinum(II) dichloride ammonia tetra-solvate.

ABSTRACT: The title compound, [Pt(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt PtCl2. The platinum cation is coordinated by four ammonia mol-ecules, forming a square-planar complex. The chloride anions are surrounded by nine ammonia mol-ecules, either bound within the platinum complex or solvent mol-ecules. The solvent ammonia mol-ecules are packed in such a way that an extended network of N-H?N and N-H?Cl hydrogen bonds is formed. The structure is isotypic with [Pd(NH3)4]Cl2·4NH3 [Grassl & Korber (2014). Acta Cryst. E70, i32].

SUBMITTER: Grassl T

PROVIDER: S-EPMC4120569 | biostudies-other | 2014 Jul

REPOSITORIES: biostudies-other

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Tetra-ammineplatinum(II) dichloride ammonia tetra-solvate.

Grassl Tobias T Korber Nikolaus N

Acta crystallographica. Section E, Structure reports online 20140607 Pt 7

The title compound, [Pt(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt PtCl2. The platinum cation is coordinated by four ammonia mol-ecules, forming a square-planar complex. The chloride anions are surrounded by nine ammonia mol-ecules, either bound within the platinum complex or solvent mol-ecules. The solvent ammonia mol-ecules are packed in such a way that an extended network of N-H⋯N and N-H⋯Cl hydrogen bonds is formed. The structure is isotypic with [Pd(NH3)4]Cl2·4NH3 [Gra ...[more]

PMID: 25161504

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