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Relay cross metathesis reactions of vinylphosphonates.

ABSTRACT: Dimethyl (?-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism.

SUBMITTER: Malla RK 

PROVIDER: S-EPMC4168886 | biostudies-other | 2014

REPOSITORIES: biostudies-other

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Relay cross metathesis reactions of vinylphosphonates.

Malla Raj K RK   Ridenour Jeremy N JN   Spilling Christopher D CD  

Beilstein journal of organic chemistry 20140819

Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism. ...[more]