Enhanced electrocatalytic performance for oxygen reduction via active interfaces of layer-by-layered titanium nitride/titanium carbonitride structures.

ABSTRACT: Cathode materials always limit the performance of fuel cells while the commercial platinum-based catalysts hardly meet the requirements of low cost, durable and stable. Here a non-precious metal oxygen reduction reaction (ORR) electocatalyst based on titanium nitride/titanium carbonitride hierarchical structures (TNTCNHS) is demonstrated as high activity as Pt/C. In alkaline condition, tuning interface/mass ratio of TiN/TiCN, we observed the onset potential of ~0.93?V vs. RHE and a limit diffusion current density of ~5.1?mA cm(-2) (at a rotating speed of 1600?rpm) on TNTCNHS with a relative low catalyst loading of ~0.1?mg cm(-2). The kinetic current, durability and tolerance to crossover effect studies reveal even more efficient than carbon-supported platinum. The architecture fabrication for such electrocatalyst is easy to realize in industrial-scale facilities, for the use of chemical vapor deposition (CVD) technique could support a huge area production (more than 10000?cm(2) for one pot) to satisfy the enormous market requirements in the future.

SUBMITTER: Jin Z 

PROVIDER: S-EPMC4205842 | biostudies-other | 2014

REPOSITORIES: biostudies-other