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Crystal structure of bis-(di-methyl-ammonium) hexa-aqua-nickel(II) bis-(sulfate) dihydrate.

ABSTRACT: In the title salt, (C2H8N)2[Ni(H2O)6)](SO4)2·2H2O, the Ni(II) cation is located on a centre of inversion and exhibits a slightly distorted octa-hedral arrangement of water mol-ecules. The Ni-O bond lengths in the complex [Ni(H2O)6](2+) cation show a distribution as in the related Tutton salt (NH4)2[Ni(H2O)6](SO4)2, but are longer in average [2.056?(13) versus 2.037?(12)?Å]. The noncoordinating water mol-ecules and di-methyl-ammonium cations connect the sulfate and [Ni(H2O)6](2+) octa-hedra via O-H?O and N-H?O hydrogen bonds from weak up to medium strength into a three-dimensional framework whereby the complex metal cations and sulfate anions are arranged in sheets parallel (001).

SUBMITTER: Held P

PROVIDER: S-EPMC4257308 | biostudies-other | 2014 Nov

REPOSITORIES: biostudies-other

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Crystal structure of bis-(di-methyl-ammonium) hexa-aqua-nickel(II) bis-(sulfate) dihydrate.

Held Peter P

Acta crystallographica. Section E, Structure reports online 20141024 Pt 11

In the title salt, (C2H8N)2[Ni(H2O)6)](SO4)2·2H2O, the Ni(II) cation is located on a centre of inversion and exhibits a slightly distorted octa-hedral arrangement of water mol-ecules. The Ni-O bond lengths in the complex [Ni(H2O)6](2+) cation show a distribution as in the related Tutton salt (NH4)2[Ni(H2O)6](SO4)2, but are longer in average [2.056 (13) versus 2.037 (12) Å]. The noncoordinating water mol-ecules and di-methyl-ammonium cations connect the sulfate and [Ni(H2O)6](2+) octa-hedra via O ...[more]

PMID: 25484758

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