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Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

ABSTRACT: In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C-C distance of 1.5339?(11)?Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

SUBMITTER: Man WY

PROVIDER: S-EPMC4257441 | biostudies-other | 2014 Dec

REPOSITORIES: biostudies-other

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Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

Man Wing Y WY Rosair Georgina M GM Welch Alan J AJ

Acta crystallographica. Section E, Structure reports online 20141105 Pt 12

In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C-C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3. ...[more]

PMID: 25552965

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