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Tuning structural instability toward enhanced magnetocaloric effect around room temperature in MnCo(1-x)Zn(x)Ge.


ABSTRACT: Magnetocaloric effect is the phenomenon that temperature change of a magnetic material is induced by application of a magnetic field. This effect can be applied to environmentally-benign magnetic refrigeration technology. Here we show a key role of magnetic-field-induced structural instability in enhancing the magnetocaloric effect for MnCo(1-x)Zn(x)Ge alloys (x = 0-0.05). The increase in x rapidly reduces the martensitic transition temperature while keeping the ferromagnetic transition around room temperature. Fine tuning of x around x = 0.03 leads to the concomitant structural and ferromagnetic transition in a cooling process, giving rise to enhanced magnetocaloric effect as well as magnetic-field-induced structural transition. Analyses of the structural phase diagrams in the T-H plane in terms of Landau free-energy phenomenology accounts for the characteristic x-dependence of the observed magnetocaloric effect, pointing to the importance of the magnetostructural coupling for the design of high-performance magnetocalorics.

SUBMITTER: Choudhury D 

PROVIDER: S-EPMC4269893 | biostudies-other | 2014

REPOSITORIES: biostudies-other

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