Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Non-uniform space charge limited current injection into a nano contact solid.

ABSTRACT: We have developed a two-dimensional (2D) non-uniform model to study the space charge limited (SCL) current injection into a trap-filled solid of nano-contact, such as organic materials and dielectrics. Assuming a solid of length D with a contact of width W, the enhancement over the well-known 1D uniform model is calculated as a function of W/D for different material properties, such as the dielectric constant (ε) and the trap distribution. The non-uniform current density profile due to edge effect is predicted. The findings reported here are different from the prior uniform 2D models, which are significant for small W/D when the size of the contact reaching nanometer scale, i.e. W = 50 nm for D = 1 μm. This model will be useful for the characterization of carrier mobility and properties of traps, which are critical to many novel devices (with small nano-contact) operating in the space charge limited condition reporting in novel device and its applications. Empirical formulas are given for future comparison with experimental results.

SUBMITTER: Zhu YB

PROVIDER: S-EPMC4361851 | biostudies-other | 2015

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

The space charge limited current and huge linear magnetoresistance in silicon.

Project description:Huge magnetoresistance in space charge regime attracts broad interest on non-equilibrium carrier transport under high electric field. However, the accurate fitting for the current-voltage curves from Ohmic to space charge regime under magnetic fields has not been achieved quantitatively. We conjecture that the localized intensive charge dynamic should be taken into consideration. Here, by introducing a field-dependent dielectric constant, for the first time, we successfully simulate the current-voltage curves of covalent crystal silicon wafers under different magnetic fields (0-1 Tesla). The simulation reveals that the optical phonon, instead of the acoustic phonon, plays a major role for the carriers transport under magnetic fields in space charge regime.

| S-EPMC5768776 | biostudies-literature

Influence of diffusion on space-charge-limited current measurements in organic semiconductors.

Project description:Numerical simulations of current-voltage curves in electron-only devices are used to discuss the influence of charged defects on the information derived from fitting space-charge-limited current models to the data. Charged, acceptor-like defects lead to barriers impeding the flow of electrons in electron-only devices and therefore lead to a reduced current that is similar to the situation where the device has a built-in voltage. This reduced current will lead to an underestimation of the mobilities and an overestimation of characteristic tail slopes if analytical equations are used to analyze the data. Correcting for the barrier created by the charged defects can, however, be a successful way to still be able to obtain reasonably accurate mobility values.

| S-EPMC3628774 | biostudies-literature

Space Charge-Limited Current Transport Mechanism in Crossbar Junction Embedding Molecular Spin Crossovers.

Project description:Spin crossover complexes are among the most studied classes of molecular switches and have attracted considerable attention for their potential technological use as active units in multifunctional devices. A fundamental step toward their practical implementation is the integration in macroscopic devices adopting hybrid vertical architectures. First, the physical properties of technological interest shown by these materials in the bulk phase have to be retained once they are deposited on a solid surface. Herein, we describe the study of a hybrid molecular inorganic junction embedding the spin crossover complex [Fe(qnal)2] (qnal = quinoline-naphthaldehyde) as an active switchable thin film sandwiched within energy-optimized metallic electrodes. In these junctions, developed and characterized with the support of state of the art techniques including synchrotron Mössbauer source (SMS) spectroscopy and focused-ion beam scanning transmission electron microscopy, we observed that the spin state conversion of the Fe(II)-based spin crossover film is associated with a transition from a space charge-limited current (SCLC) transport mechanism with shallow traps to a SCLC mechanism characterized by the presence of an exponential distribution of traps concomitant with the spin transition temperature.

| S-EPMC8008390 | biostudies-literature

Revealing Charge Carrier Mobility and Defect Densities in Metal Halide Perovskites via Space-Charge-Limited Current Measurements.

Project description:Space-charge-limited current (SCLC) measurements have been widely used to study the charge carrier mobility and trap density in semiconductors. However, their applicability to metal halide perovskites is not straightforward, due to the mixed ionic and electronic nature of these materials. Here, we discuss the pitfalls of SCLC for perovskite semiconductors, and especially the effect of mobile ions. We show, using drift-diffusion (DD) simulations, that the ions strongly affect the measurement and that the usual analysis and interpretation of SCLC need to be refined. We highlight that the trap density and mobility cannot be directly quantified using classical methods. We discuss the advantages of pulsed SCLC for obtaining reliable data with minimal influence of the ionic motion. We then show that fitting the pulsed SCLC with DD modeling is a reliable method for extracting mobility, trap, and ion densities simultaneously. As a proof of concept, we obtain a trap density of 1.3 × 1013 cm-3, an ion density of 1.1 × 1013 cm-3, and a mobility of 13 cm2 V-1 s-1 for a MAPbBr3 single crystal.

| S-EPMC8043077 | biostudies-literature

Electrostatically driven fog collection using space charge injection.

Project description:Fog collection can be a sustainable solution to water scarcity in many regions around the world. Most proposed collectors are meshes that rely on inertial collision for droplet capture and are inherently limited by aerodynamics. We propose a new approach in which we introduce electrical forces that can overcome aerodynamic drag forces. Using an ion emitter, we introduce a space charge into the fog to impart a net charge to the incoming fog droplets and direct them toward a collector using an imposed electric field. We experimentally measure the collection efficiency on single wires, two-wire systems, and meshes and propose a physical model to quantify it. We identify the regimes of optimal collection and provide insights into designing effective fog harvesting systems.

| S-EPMC5993475 | biostudies-literature

Spin-current nano-oscillator based on nonlocal spin injection.

Project description:Nonlocal spin injection has been recognized as an efficient mechanism for creation of pure spin currents not tied to the electrical charge transfer. Here we demonstrate experimentally that it can induce coherent magnetization dynamics, which can be utilized for the implementation of novel microwave nano-sources for spintronic and magnonic applications. We show that such sources exhibit a small oscillation linewidth and are tunable over a wide frequency range by the static magnetic field. Spatially resolved measurements of the dynamical magnetization indicate a relatively large oscillation area, resulting in a high stability of the oscillation with respect to thermal fluctuations. We propose a simple quasilinear dynamical model that reproduces well the oscillation characteristics.

| S-EPMC4341221 | biostudies-other

Space-charge-limited electron and hole currents in hybrid organic-inorganic perovskites.

Project description:Hybrid organic-inorganic perovskites are promising materials for the application in solar cells and light-emitting diodes. However, the basic current-voltage behavior for electrons and holes is still poorly understood in these semiconductors due to their mixed electronic-ionic character. Here, we present the analysis of space-charge-limited electron and hole currents in the archetypical perovskite methyl ammonium lead iodide (MAPbI3). We demonstrate that the frequency dependence of the permittivity plays a crucial role in the analysis of space-charge-limited currents and their dependence on voltage scan rate and temperature. Using a mixed electronic-ionic device model based on experimentally determined parameters, the current-voltage characteristics of single-carrier devices are accurately reproduced. Our results reveal that in our solution processed MAPbI3 thin films transport of electrons dominates over holes. Furthermore, we show that the direction of the hysteresis in the current-voltage characteristics provides a fingerprint for the sign of the dominant moving ionic species.

| S-EPMC7419305 | biostudies-literature

Space-Charge Layers in All-Solid-State Batteries; Important or Negligible?

Project description:All-solid state batteries have the promise to increase the safety of Li-ion batteries. A prerequisite for high-performance all-solid-state batteries is a high Li-ion conductivity through the solid electrolyte. In recent decades, several solid electrolytes have been developed which have an ionic conductivity comparable to that of common liquid electrolytes. However, fast charging and discharging of all-solid-state batteries remains challenging. This is generally attributed to poor kinetics over the electrode-solid electrolyte interface because of poorly conducting decomposition products, small contact areas, or space-charge layers. To understand and quantify the role of space-charge layers in all-solid-state batteries a simple model is presented which allows to asses the interface capacitance and resistance caused by the space-charge layer. The model is applied to LCO (LiCoO2) and graphite electrodes in contact with an LLZO (Li7La3Zr2O12) and LATP (Li1.2Al0.2Ti1.8(PO4)3) solid electrolyte at several voltages. The predictions demonstrate that the space-charge layer for typical electrode-electrolyte combinations is about a nanometer in thickness, and the consequential resistance for Li-ion transport through the space-charge layer is negligible, except when layers completely depleted of Li-ions are formed in the solid electrolyte. This suggests that space-charge layers have a negligible impact on the performance of all-solid-state batteries.

| S-EPMC6199673 | biostudies-literature

Ultralow dark current in near-infrared perovskite photodiodes by reducing charge injection and interfacial charge generation.

Project description:Metal halide perovskite photodiodes (PPDs) offer high responsivity and broad spectral sensitivity, making them attractive for low-cost visible and near-infrared sensing. A significant challenge in achieving high detectivity in PPDs is lowering the dark current density (JD) and noise current (in). This is commonly accomplished using charge-blocking layers to reduce charge injection. By analyzing the temperature dependence of JD for lead-tin based PPDs with different bandgaps and electron-blocking layers (EBL), we demonstrate that while EBLs eliminate electron injection, they facilitate undesired thermal charge generation at the EBL-perovskite interface. The interfacial energy offset between the EBL and the perovskite determines the magnitude and activation energy of JD. By increasing this offset we realized a PPD with ultralow JD and in of 5 × 10-8 mA cm-2 and 2 × 10-14 A Hz-1/2, respectively, and wavelength sensitivity up to 1050 nm, establishing a new design principle to maximize detectivity in perovskite photodiodes.

| S-EPMC8671406 | biostudies-literature

Switching from weakly to strongly limited injection in self-aligned, nano-patterned organic transistors.

Project description:Organic thin-film transistors for high frequency applications require large transconductances in combination with minimal parasitic capacitances. Techniques aiming at eliminating parasitic capacitances are prone to produce a mismatch between electrodes, in particular gaps between the gate and the interlayer electrodes. While such mismatches are typically undesirable, we demonstrate that, in fact, device structures with a small single-sided interlayer electrode gap directly probe the detrimental contact resistance arising from the presence of an injection barrier. By employing a self-alignment nanoimprint lithography technique, asymmetric coplanar organic transistors with an intentional gap of varying size (< 0.2??m) between gate and one interlayer electrode are fabricated. An electrode overlap exceeding 1??m with the other interlayer has been kept. Gaps, be them source or drain-sided, do not preclude transistor operation. The operation of the device with a source-gate gap reveals a current reduction up to two orders of magnitude compared to a source-sided overlap. Drift-diffusion based simulations reveal that this marked reduction is a consequence of a weakened gate-induced field at the contact which strongly inhibits injection.

| S-EPMC5037384 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data