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Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

ABSTRACT: Knowledge of planetary differentiation is crucial for understanding the chemical and thermal evolution of terrestrial planets. The (176)Lu-(176)Hf radioactive decay system has been widely used to constrain the timescales and mechanisms of silicate differentiation on Earth, but the data interpretation requires accurate estimation of Hf isotope evolution of the bulk Earth. Because both Lu and Hf are refractory lithophile elements, the isotope evolution can be potentially extrapolated from the present-day (176)Hf/(177)Hf and (176)Lu/(177)Hf in undifferentiated chondrite meteorites. However, these ratios in chondrites are highly variable due to the metamorphic redistribution of Lu and Hf, making it difficult to ascertain the correct reference values for the bulk Earth. In addition, it has been proposed that chondrites contain excess (176)Hf due to the accelerated decay of (176)Lu resulting from photoexcitation to a short-lived isomer. If so, the paradigm of a chondritic Earth would be invalid for the Lu-Hf system. Herein we report the first, to our knowledge, high-precision Lu-Hf isotope analysis of meteorite crystalline zircon, a mineral that is resistant to metamorphism and has low Lu/Hf. We use the meteorite zircon data to define the Solar System initial (176)Hf/(177)Hf (0.279781 ± 0.000018) and further to identify pristine chondrites that contain no excess (176)Hf and accurately represent the Lu-Hf system of the bulk Earth ((176)Hf/(177)Hf = 0.282793 ± 0.000011; (176)Lu/(177)Hf = 0.0338 ± 0.0001). Our results provide firm evidence that the most primitive Hf in terrestrial zircon reflects the development of a chemically enriched silicate reservoir on Earth as far back as 4.5 billion years ago.

SUBMITTER: Iizuka T

PROVIDER: S-EPMC4418863 | biostudies-other | 2015 Apr

REPOSITORIES: biostudies-other

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Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

Iizuka Tsuyoshi T Yamaguchi Takao T Hibiya Yuki Y Amelin Yuri Y

Proceedings of the National Academy of Sciences of the United States of America 20150413 17

Knowledge of planetary differentiation is crucial for understanding the chemical and thermal evolution of terrestrial planets. The (176)Lu-(176)Hf radioactive decay system has been widely used to constrain the timescales and mechanisms of silicate differentiation on Earth, but the data interpretation requires accurate estimation of Hf isotope evolution of the bulk Earth. Because both Lu and Hf are refractory lithophile elements, the isotope evolution can be potentially extrapolated from the pres ...[more]

PMID: 25870298

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Project description:Earth's core formation set the initial compositions of the core and mantle. Various aspects of core formation, such as the degree of metal-silicate equilibration, oxygen fugacity, and depth of equilibration, have significant consequences for the resulting compositions, yet are poorly constrained. The Hf-W isotopic system can provide unique constraints on these aspects relative to other geochemical or geophysical methods. Here we model the Hf-W isotopic evolution of the Earth, improving over previous studies by combining a large number of N-body simulations of planetary accretion with a core formation model that includes self-consistent evolution of oxygen fugacity and a partition coefficient of tungsten that evolves with changing pressure, temperature, composition, and oxygen fugacity. The effective average fraction of equilibrating metal is constrained to be k > 0.2 for a range of equilibrating silicate masses (for canonical accretion scenarios), and is likely <0.55 if the Moon formed later than 65 Ma. These values of k typically correspond to an effective equilibration depth of ~0.5-0.7× the evolving core-mantle boundary pressure as the planet grows. The average mass of equilibrating silicate was likely at least 3× the impactor's silicate mass. Equilibration temperature, initial fO2 initial differentiation time, semimajor axis, and planetary mass (above ~0.9 M⊕) have no systematic effect on the 182W anomaly, or on f Hf/W (except for fO2), when applying the constraint that the model must reproduce Earth's mantle W abundance. There are strong tradeoffs between the effects of k, equilibrating silicate mass, depth of equilibration, and timing of core formation, so the terrestrial Hf-W isotopic system should be interpreted with caution when used as a chronometer of Earth's core formation. Because of these strong tradeoffs, the Earth's tungsten anomaly can be reproduced for Moon-forming impact timescales spanning at least 10-175 Ma. Early Moon formation ages require a higher degree of metal-silicate equilibration to produce Earth's 182W anomaly.

Dataset Information

Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

Publications

Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

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