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Le nitrate double NaRb2(NO3)3, compose intermediaire du systeme binaire isobare NaNO3 + RbNO3: etudes thermiques et cristallographiques.


ABSTRACT: Crystallographic and thermodynamic investigations of the binary (NaNO3 + RbNO3) phase diagram at atmospheric pressure reveal the existence of an inter-mediate compound NaRb2(NO3)3 (sodium dirubidium trinitrate) previously predicted and now reported experimentally for the first time. According to a DSC analysis, the compound exhibits three allotropic forms. In its low-temperature allotropic form (? form, ortho-rhom-bic) there are two Rb (m.. site symmetry) and one Na (m..) independent crystallographic positions and three planar nitrate groups. The bond-valence-sum calculations for all atoms agree well with their oxidation states. The Rb cations are located in the (100) plane at x = ½ with 11 oxygen coordination. The Na ones are in the same plane at x = 0 and are coordinated to eight O atoms from six nitrate groups. The charge-distribution method has been used to evaluate the degree of distortion of the alkali polyhedra.

SUBMITTER: Ksiksi N 

PROVIDER: S-EPMC4420088 | biostudies-other | 2015 May

REPOSITORIES: biostudies-other

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Le nitrate double NaRb2(NO3)3, composé intermédiaire du système binaire isobare NaNO3 + RbNO3: études thermiques et cristallographiques.

Ksiksi Nesrine N   Driss Mohamed M   Hellali Dalila D   Guesmi Abderrahmen A   Zamali Hmida H  

Acta crystallographica. Section E, Crystallographic communications 20150409 Pt 5


Crystallographic and thermodynamic investigations of the binary (NaNO3 + RbNO3) phase diagram at atmospheric pressure reveal the existence of an inter-mediate compound NaRb2(NO3)3 (sodium dirubidium trinitrate) previously predicted and now reported experimentally for the first time. According to a DSC analysis, the compound exhibits three allotropic forms. In its low-temperature allotropic form (α form, ortho-rhom-bic) there are two Rb (m.. site symmetry) and one Na (m..) independent crystallogr  ...[more]

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