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Crystal structure of bis-(fluoro-sulfato-?O)xenon(II), Xe(SO3F)2.

ABSTRACT: Thermally unstable Xe(SO3F)2 has been prepared by the reaction of XeF2 with HSO3F. Single crystals were obtained from HSO3F by slow cooling in a sealed tube. The mol-ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro-sulfate tetra-hedra in an almost linear fashion [O-Xe-O = 179.13?(4)°]. The crystal packing is strongly influenced by inter-molecular van der Waals forces.

SUBMITTER: Malischewski M 

PROVIDER: S-EPMC4438818 | biostudies-other | 2015 Apr

REPOSITORIES: biostudies-other

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Crystal structure of bis-(fluoro-sulfato-κO)xenon(II), Xe(SO3F)2.

Malischewski Moritz M   Seppelt Konrad K  

Acta crystallographica. Section E, Crystallographic communications 20150314 Pt 4

Thermally unstable Xe(SO3F)2 has been prepared by the reaction of XeF2 with HSO3F. Single crystals were obtained from HSO3F by slow cooling in a sealed tube. The mol-ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro-sulfate tetra-hedra in an almost linear fashion [O-Xe-O = 179.13 (4)°]. The crystal packing is strongly influenced by inter-molecular van der Waals forces. ...[more]