Unknown

Dataset Information

0

Crystal structure of an unknown solvate of bis-(tetra-n-butyl-ammonium) [N,N'-(4-tri-fluoro-methyl-1,2-phenyl-ene)bis-(oxamato)-?(4) O,N,N',O']nickelate(II).

ABSTRACT: In the title compound, [N(C4H9)4]2[Ni(C11H3F3N2O6)] or [N(n-Bu)4]2[Ni(topbo)] [n-Bu = n-butyl and topbo = 4-tri-fluoro-methyl-1,2-phenyl-enebis(oxamate)], the Ni(2+) cation is coordinated by two deprotonated amido N atoms and two carboxyl-ate O atoms, setting up a slightly distorted square-planar coordination environment. The [Ni(topbo](2-) anion lies on a twofold rotation axis. Due to an incompatibility with the point-group symmetry of the complete mol-ecule, orientational disorder of the CF3 group is observed. The tetra-hedral ammonium cations and the anion are linked by weak inter-molecular C-H?O and C-H?F hydrogen-bonding inter-actions into a three-dimensional network. A region of electron density was treated with the SQUEEZE procedure in PLATON [Spek (2015). Acta Cryst. C71, 9-18] following unsuccessful attempts to model it as plausible solvent mol-ecule(s). The given chemical formula and other crystal data do not take into account the unknown solvent mol-ecule.

SUBMITTER: Eya'ane Meva F 

PROVIDER: S-EPMC4459374 | biostudies-other | 2015 Jun

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Crystal structure of an unknown solvate of bis-(tetra-n-butyl-ammonium) [N,N'-(4-tri-fluoro-methyl-1,2-phenyl-ene)bis-(oxamato)-κ(4) O,N,N',O']nickelate(II).

Eya'ane Meva François F   Schaarschmidt Dieter D   Rüffer Tobias T  

Acta crystallographica. Section E, Crystallographic communications 20150507 Pt 6

In the title compound, [N(C4H9)4]2[Ni(C11H3F3N2O6)] or [N(n-Bu)4]2[Ni(topbo)] [n-Bu = n-butyl and topbo = 4-tri-fluoro-methyl-1,2-phenyl-enebis(oxamate)], the Ni(2+) cation is coordinated by two deprotonated amido N atoms and two carboxyl-ate O atoms, setting up a slightly distorted square-planar coordination environment. The [Ni(topbo](2-) anion lies on a twofold rotation axis. Due to an incompatibility with the point-group symmetry of the complete mol-ecule, orientational disorder of the CF3 g  ...[more]

Similar Datasets

Unknown 1-Butyl-pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3246985 | biostudies-literature
Unknown Bis(tetra-butyl-ammonium) bis-(3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ato-?S,S')cadmate(II) 0.25-hydrate.
| S-EPMC3050421 | biostudies-literature
Unknown 1-(2-Fluoro-benzyl-ideneamino)pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC2977634 | biostudies-literature
Unknown Tetraphenyl-arsonium cis-bis-[1,2-bis-(tri-fluoro-meth-yl)ethene-1,2-dithiol-ato]platinate(II).
| S-EPMC2969384 | biostudies-literature
Unknown 3,3'-Di-n-butyl-1,1'-(p-phenyl-ene-dimethyl-ene)diimidazolium bis-(hexa-fluoro-phosphate).
| S-EPMC2983963 | biostudies-literature
Unknown [1,4-Phenyl-enebis(methyl-ene)]bis-(tri-phenyl-phospho-nium) bis-(tetra-fluoro-borate).
| S-EPMC3239032 | biostudies-literature
Unknown catena-Poly[[[bis-(methanol-?O)bis-(seleno-cyanato-?N)manganese(II)]-?-1,2-bis-(pyridin-4-yl)eth-ene-?(2) N:N'] 1,2-bis-(pyridin-4-yl)eth-ene mono-solvate].
| S-EPMC3684882 | biostudies-literature
Unknown 6,6'-Di-tert-butyl-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenol.
| S-EPMC2972107 | biostudies-literature
Unknown Tetra-n-butyl-ammonium bis-(2,2-dicyano-ethyl-ene-1,1-dithiol-ato)palladium(II).
| S-EPMC2959997 | biostudies-literature
Unknown Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato)platinum(II).
| S-EPMC2959936 | biostudies-literature