Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

First Principles Prediction of Topological Phases in Thin Films of Pyrochlore Iridates.

ABSTRACT: While the theoretical and experimental study of topological phases of matter has experienced rapid growth over the last few years, there remain a relatively small number of material classes that have been experimentally shown to host these phases. Most of these materials contain bismuth, and none so far are oxides. In this work we make materials-specific predictions for topological phases using density functional theory combined with Hartree-Fock theory that includes the full orbital structure of the relevant iridium d-orbitals and the strong but finite spin-orbit coupling strength. We find Y2Ir2O7 bilayer and trilayer films grown along the [111] direction can support topological metallic phases with a direct gap of up to 0.05 eV, which could potentially bring transition metal oxides to the fore as a new class of topological materials with potential applications in oxide electronics.

SUBMITTER: Hu X

PROVIDER: S-EPMC4468522 | biostudies-other | 2015

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Magnetic-field induced multiple topological phases in pyrochlore iridates with Mott criticality.

Project description:The interplay between electron correlation and spin-orbit coupling in solids has been proven to be an abundant gold mine for emergent topological phases. Here we report the results of systematic magnetotransport study on bandwidth-controlled pyrochlore iridates R2Ir2O7 near quantum metal-insulator transition (MIT). The application of a magnetic field along [001] crystallographic direction (H//[001]) significantly decreases resistivity while producing a unique Hall response, which indicates the emergence of the novel semi-metallic state in the course of the magnetic transformation from all-in all-out (AIAO, 4/0) to 2-in 2-out (2/2) spin configuration. For H//[111] that favours 3-in 1-out (3/1) configuration, by contrast, the resistivity exhibits saturation at a relatively high value typical of a semimetal. The observed properties can be identified to reflect the emergence of multiple Weyl semimetal states with varying numbers of Weyl points and line nodes in respective spin configurations. With tuning effective bandwidth, all these states appear to concentrate around the quantum MIT region, which may open a promising venue for topological phenomena and functions.

| S-EPMC5458080 | biostudies-literature

Odd-parity magnetoresistance in pyrochlore iridate thin films with broken time-reversal symmetry.

Project description:A new class of materials termed topological insulators have been intensively investigated due to their unique Dirac surface state carrying dissipationless edge spin currents. Recently, it has been theoretically proposed that the three dimensional analogue of this type of band structure, the Weyl Semimetal phase, is materialized in pyrochlore oxides with strong spin-orbit coupling, accompanied by all-in-all-out spin ordering. Here, we report on the fabrication and magnetotransport of Eu2Ir2O7 single crystalline thin films. We reveal that one of the two degenerate all-in-all-out domain structures, which are connected by time-reversal operation, can be selectively formed by the polarity of the cooling magnetic field. Once formed, the domain is robust against an oppositely polarised magnetic field, as evidenced by an unusual odd field dependent term in the magnetoresistance and an anomalous term in the Hall resistance. Our findings pave the way for exploring the predicted novel quantum transport phenomenon at the surfaces/interfaces or magnetic domain walls of pyrochlore iridates.

| S-EPMC4426595 | biostudies-literature

Designing functionality in perovskite thin films using ion implantation techniques: Assessment and insights from first-principles calculations.

Project description:Recent experimental findings have demonstrated that low doses of low energy helium ions can be used to tailor the structural and electronic properties of single crystal films. These initial studies have shown that changes to lattice expansion were proposed to be the direct result of chemical pressure originating predominantly from the implanted He applying chemical pressure at interstitial sites. However, the influence of possible secondary knock-on damage arising from the He atoms transferring energy to the lattice through nuclear-nuclear collision with the crystal lattice remains largely unaddressed. Here, we study SrRuO3 to provide a comprehensive examination of the impact of common defects on structural and electronic properties. We found that, while interstitial He can modify the properties, a dose significantly larger than those reported in experimental studies would be required. Our study suggests that true origin of the observed changes is from combination of secondary defects created during He implantation. Of particular importance, we observe that different defect types can generate greatly varied local electronic structures and that the formation energies and migration energy barriers vary by defect type. Thus, we may have identified a new method of selectively inducing controlled defect complexes into single crystal materials.

| S-EPMC5593984 | biostudies-literature

Strain engineering of the magnetic multipole moments and anomalous Hall effect in pyrochlore iridate thin films.

Project description:The recent observation of the anomalous Hall effect (AHE) without notable magnetization in antiferromagnets has suggested that ferromagnetic ordering is not a necessary condition. Thus, recent theoretical studies have proposed that higher-rank magnetic multipoles formed by clusters of spins (cluster multipoles) can generate the AHE without magnetization. Despite such an intriguing proposal, controlling the unconventional AHE by inducing these cluster multipoles has not been investigated. Here, we demonstrate that strain can manipulate the hidden Berry curvature effect by inducing the higher-rank cluster multipoles in spin-orbit-coupled antiferromagnets. Observing the large AHE on fully strained antiferromagnetic Nd2Ir2O7 thin films, we prove that strain-induced cluster T 1-octupoles are the only source of observed AHE. Our results provide a previously unidentified pathway for generating the unconventional AHE via strain-induced magnetic structures and establish a platform for exploring undiscovered topological phenomena via strain in correlated materials.

| S-EPMC7439458 | biostudies-literature

Oxidation Effects in Rare Earth Doped Topological Insulator Thin Films.

Project description:The breaking of time-reversal symmetry (TRS) in topological insulators is a prerequisite for unlocking their exotic properties and for observing the quantum anomalous Hall effect (QAHE). The incorporation of dopants which exhibit magnetic long-range order is the most promising approach for TRS-breaking. REBiTe3, wherein 50% of the Bi is substitutionally replaced by a RE atom (RE = Gd, Dy, and Ho), is a predicted QAHE system. Despite the low solubility of REs in bulk crystals of a few %, highly doped thin films have been demonstrated, which are free of secondary phases and of high crystalline quality. Here we study the effects of exposure to atmosphere of rare earth-doped Bi2(Se, Te)3 thin films using x-ray absorption spectroscopy. We demonstrate that these RE dopants are all trivalent and effectively substitute for Bi(3+) in the Bi2(Se, Te)3 matrix. We find an unexpected high degree of sample oxidation for the most highly doped samples, which is not restricted to the surface of the films. In the low-doping limit, the RE-doped films mostly show surface oxidation, which can be prevented by surface passivation, encapsulation, or in-situ cleaving to recover the topological surface state.

| S-EPMC4783712 | biostudies-literature

Optical control of spin-polarized photocurrent in topological insulator thin films.

Project description:Dirac electrons in topological insulators (TIs) provide one possible avenue to achieve control of photocurrents and spin currents without the need to apply external fields by utilizing characteristic spin-momentum locking. However, for TI crystals with electrodes it is actually difficult to characterize the net flow of spin-polarized photocurrents because of the coexistence of surface carriers and bulk carriers generated by optical excitations. We demonstrate here that the net flow directions of spin-polarized photocurrents in TI polycrystalline thin films without electrodes can be precisely and intentionally controlled by the polarization of the excitation pulse alone, which is characterized by performing time-domain terahertz (THz) wave measurements and time-resolved magneto-optical Kerr rotation measurements that are non-contact methods. We show that the amplitudes of s-polarized THz waves radiated from photocurrents under right- and left-circularly polarized excitations are inverted relative to one another. Moreover, we observe the inversion of time-resolved magneto-optical Kerr rotation signals between the two excitations. Our results will open the way as innovative methods to control spin-polarized electrons in optoelectronic and spintronic TI devices without the need to apply external fields.

| S-EPMC6193961 | biostudies-literature

Massive Dirac Fermion Observed in Lanthanide-Doped Topological Insulator Thin Films.

Project description:The breaking of time reversal symmetry (TRS) in three-dimensional (3D) topological insulators (TIs), and thus the opening of a 'Dirac-mass gap' in the linearly dispersed Dirac surface state, is a prerequisite for unlocking exotic physical states. Introducing ferromagnetic long-range order by transition metal doping has been shown to break TRS. Here, we present the study of lanthanide (Ln) doped Bi2Te3, where the magnetic doping with high-moment lanthanides promises large energy gaps. Using molecular beam epitaxy, single-crystalline, rhombohedral thin films with Ln concentrations of up to ~35%, substituting on Bi sites, were achieved for Dy, Gd, and Ho doping. Angle-resolved photoemission spectroscopy shows the characteristic Dirac cone for Gd and Ho doping. In contrast, for Dy doping above a critical doping concentration, a gap opening is observed via the decreased spectral intensity at the Dirac point, indicating a topological quantum phase transition persisting up to room-temperature.

| S-EPMC4621505 | biostudies-literature

High performing flexible optoelectronic devices using thin films of topological insulator.

Project description:Topological insulators (TIs) possess exciting nonlinear optical properties due to presence of metallic surface states with the Dirac fermions and are predicted as a promising material for broadspectral phodotection ranging from UV (ultraviolet) to deep IR (infrared) or terahertz range. The recent experimental reports demonstrating nonlinear optical properties are mostly carried out on non-flexible substrates and there is a huge demand for the fabrication of high performing flexible optoelectronic devices using new exotic materials due to their potential applications in wearable devices, communications, sensors, imaging etc. Here first time we integrate the thin films of TIs (Bi2Te3) with the flexible PET (polyethylene terephthalate) substrate and report the strong light absorption properties in these devices. Owing to small band gap material, evolving bulk and gapless surface state conduction, we observe high responsivity and detectivity at NIR (near infrared) wavelengths (39 A/W, 6.1 × 108 Jones for 1064 nm and 58 A/W, 6.1 × 108 Jones for 1550 nm). TIs based flexible devices show that photocurrent is linearly dependent on the incident laser power and applied bias voltage. Devices also show very fast response and decay times. Thus we believe that the superior optoelectronic properties reported here pave the way for making TIs based flexible optoelectronic devices.

| S-EPMC7804467 | biostudies-literature

Epitaxial growth of iridate pyrochlore Nd2Ir2O7 films.

Project description:Epitaxial films of the pyrochlore Nd2Ir2O7 have been grown on (111)-oriented yttria-stabilized zirconia (YSZ) substrates by off-axis sputtering followed by post-growth annealing. X-ray diffraction (XRD) results demonstrate phase-pure epitaxial growth of the pyrochlore films on YSZ. Scanning transmission electron microscopy (STEM) investigation of an Nd2Ir2O7 film with a short post-annealing provides insight into the mechanism for crystallization of Nd2Ir2O7 during the post-annealing process. STEM images reveal clear pyrochlore ordering of Nd and Ir in the films. The epitaxial relationship between the YSZ and Nd2Ir2O7 is observed clearly while some interfacial regions show a thin region with polycrystalline Ir nanocrystals.

| S-EPMC4770277 | biostudies-literature

Intrinsic conduction through topological surface states of insulating Bi2Te3 epitaxial thin films.

Project description:Topological insulators represent a novel state of matter with surface charge carriers having a massless Dirac dispersion and locked helical spin polarization. Many exciting experiments have been proposed by theory, yet their execution has been hampered by the extrinsic conductivity associated with the unavoidable presence of defects in Bi2Te3 and Bi2Se3 bulk single crystals, as well as impurities on their surfaces. Here we present the preparation of Bi2Te3 thin films that are insulating in the bulk and the four-point probe measurement of the conductivity of the Dirac states on surfaces that are intrinsically clean. The total amount of charge carriers in the experiment is of the order of 10(12) cm(-2) only, and mobilities up to 4,600 cm(2)/Vs have been observed. These values are achieved by carrying out the preparation, structural characterization, angle-resolved and X-ray photoemission analysis, and temperature-dependent four-point probe conductivity measurement all in situ under ultra-high-vacuum conditions. This experimental approach opens the way to prepare devices that can exploit the intrinsic topological properties of the Dirac surface states.

| S-EPMC4210329 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data