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Reduced Graphene Oxide-Based Silver Nanoparticle-Containing Composite Hydrogel as Highly Efficient Dye Catalysts for Wastewater Treatment.

ABSTRACT: New reduced graphene oxide-based silver nanoparticle-containing composite hydrogels were successfully prepared in situ through the simultaneous reduction of GO and noble metal precursors within the GO gel matrix. The as-formed hydrogels are composed of a network structure of cross-linked nanosheets. The reported method is based on the in situ co-reduction of GO and silver acetate within the hydrogel matrix to form RGO-based composite gel. The stabilization of silver nanoparticles was also achieved simultaneously within the gel composite system. The as-formed silver nanoparticles were found to be homogeneously and uniformly dispersed on the surface of the RGO nanosheets within the composite gel. More importantly, this RGO-based silver nanoparticle-containing composite hydrogel matrix acts as a potential catalyst for removing organic dye pollutants from an aqueous environment. Interestingly, the as-prepared catalytic composite matrix structure can be conveniently separated from an aqueous environment after the reaction, suggesting the potentially large-scale applications of the reduced graphene oxide-based nanoparticle-containing composite hydrogels for organic dye removal and wastewater treatment.

SUBMITTER: Jiao T

PROVIDER: S-EPMC4505314 | biostudies-other | 2015

REPOSITORIES: biostudies-other

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Project description:Industrial effluents are a leading major threat for water contamination, subsequently which results in severe health associated risks. Hence, purifying wastewater before releasing into the water resources is essential to avoid contamination. In this study, ZnO/Cu-DPA nano-composites were prepared by altering the percentage of Cu-DPA (20%, 30%, 40%, and 50% which are denoted to be ZnO/20%Cu-DPA, ZnO/30%Cu-DPA, ZnO/40%Cu-DPA and ZnO/50%Cu-DPA) using a simple mechanical grinding process. Several spectroscopic studies were employed such as electron paramagnetic analysis (EPR), powdered X-ray diffractometer (PXRD), UV-Vis absorbance spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscope to characterize these nano-composites. The photo-catalytic activities of the prepared nano-composites were studied by degrading MB under visible light irradiation. ZnO, ZnO/20%Cu-DPA, ZnO/30%Cu-DPA, ZnO/40%Cu-DPA and ZnO/50%Cu-DPA degradation efficiencies were determined to be 71.8, 78.5, 77.1, and 66.1%, respectively. Among the composite catalysts, the ZnO/20%Cu-DPA coupled system are demonstrated the best efficiency (87%) for photo-degradation of MB within 80 min when exposed to visible light. The ZnO/Cu-DPA nano-composites had a greater MB photodegradation efficiency than pristine ZnO owing to p-n heterojunction in the linked system. Under visible light irradiation, the ZnO/20%Cu-DPA catalysed the conversion of dissolved O2 to hydroxyl radicals (OH·), triggering the reduction of MB. This suggests that ·OH is the primary specific active radical involved in the photo-catalytic decomposition of MB. Furthermore, EPR analysis indicates the existence of ·OH in the photo-catalytic system. The proposed nano-composites (ZnO/20%Cu-DPA) reusability was investigated across three cycles as the most efficient photo-catalyst. The results show that, the ZnO/Cu-DPA nano-catalyst is a potential candidate for the remediation of dirty water.

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Reduced Graphene Oxide-Based Silver Nanoparticle-Containing Composite Hydrogel as Highly Efficient Dye Catalysts for Wastewater Treatment.

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