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ABSTRACT:
SUBMITTER: Theppitak C
PROVIDER: S-EPMC4647358 | biostudies-other | 2015 Oct
REPOSITORIES: biostudies-other
Theppitak Chatphorn C Chainok Kittipong K
Acta crystallographica. Section E, Crystallographic communications 20150912 Pt 10
The title compound, [Ag2Mn(CN)4(C10H8N2)] n or Mn(bipy){Ag(CN)2}2 (bipy = 2,2'-bi-pyridine) is isostructural with Cd(bipy){Au(CN)2}2 [Guo et al. (2009 ▸). CrystEngComm, 11, 61-66]. The Mn(II) atom has crystallographically imposed twofold symmetry and a distorted octa-hedral coordination sphere consisting of six N atoms from one bi-pyridine ligand and four di-cyano-argentate(I) anions, [Ag(CN)2](-), while the Ag(I) atom of the complex anion displays the expected linear geometry. Each [Ag(CN)2](-) ...[more]