Dataset Information
HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols.
Ontology highlight
ABSTRACT:
SUBMITTER: Barreiro E
PROVIDER: S-EPMC4676292 | biostudies-other | 2015 Dec
REPOSITORIES: biostudies-other
Publications
HBF<sub>4</sub>-Catalysed Nucleophilic Substitutions of Propargylic Alcohols.
European journal of organic chemistry 20151029 34
The activity of HBF<sub>4</sub> (aqueous solution) as a catalyst in propargylation reactions is presented. Diverse types of nucleophiles were employed in order to form new C-O, C-N and C-C bonds in technical acetone and in air. Good to excellent yields and good chemoselectivities were obtained using low acid loading (typically 1 mol-%) under simple reaction conditions. ...[more]