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Crystal structure of tris-(piperidinium) hydrogen sulfate sulfate.

ABSTRACT: In the title molecular salt, 3C5H12N(+)·HSO4 (-)·SO4 (2-), each cation adopts a chair conformation. In the crystal, the hydrogen sulfate ion is connected to the sulfate ion by a strong O-H?O hydrogen bond. The packing also features a number of N-H?O hydrogen bonds, which lead to a three-dimensional network structure. The hydrogen sulfate anion accepts four hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to five separate piperidinium cations, forming seven hydrogen bonds.

SUBMITTER: Lukianova TJ

PROVIDER: S-EPMC4719810 | biostudies-other | 2015 Dec

REPOSITORIES: biostudies-other

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Crystal structure of tris-(piperidinium) hydrogen sulfate sulfate.

Lukianova Tamara J TJ Kinzhybalo Vasyl V Pietraszko Adam A

Acta crystallographica. Section E, Crystallographic communications 20151104 Pt 12

In the title molecular salt, 3C5H12N(+)·HSO4 (-)·SO4 (2-), each cation adopts a chair conformation. In the crystal, the hydrogen sulfate ion is connected to the sulfate ion by a strong O-H⋯O hydrogen bond. The packing also features a number of N-H⋯O hydrogen bonds, which lead to a three-dimensional network structure. The hydrogen sulfate anion accepts four hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to five separate piperidinium cations, forming seven hydrogen ...[more]

PMID: 26870401

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