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Crystal structure of bis-{?-1-[(E)-(3-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-?(3) N (2),O:O}bis-({1-[(E)-(3-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-?(2) N (2),O}copper(II)).

ABSTRACT: The title dinuclear Cu(II) complex, [Cu2(C17H13N2O2)4], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu?Cu separation is 3.366?(3)?Å. In the crystal, complex mol-ecules are linked via weak C-H?O hydrogen bonds, forming a layer parallel to (-101).

SUBMITTER: Chetioui S

PROVIDER: S-EPMC4719838 | biostudies-other | 2015 Dec

REPOSITORIES: biostudies-other

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Crystal structure of bis-{μ-1-[(E)-(3-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(3) N (2),O:O}bis-({1-[(E)-(3-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(2) N (2),O}copper(II)).

Chetioui Souheyla S Hamdouni Noudjoud N Bochet Christian G CG Djukic Jean-Pierre JP Bailly Corinne C

Acta crystallographica. Section E, Crystallographic communications 20151107 Pt 12

The title dinuclear Cu(II) complex, [Cu2(C17H13N2O2)4], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu⋯Cu separation is 3.366 (3) Å. In the crystal, complex mol-ecules are linked via weak C-H⋯O hydrogen bonds, forming a layer parallel to (-101). ...[more]

PMID: 26870429

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