Ontology highlight
ABSTRACT:
SUBMITTER: Rietzler B
PROVIDER: S-EPMC4719859 | biostudies-other | 2015 Dec
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Crystallographic communications 20151209 Pt 12
The title salt, [Ag(C5H8N2O2)2]PF6, was obtained by deprotonation and metalation of 1,3-di-meth-oxy-imidazolium hexa-fluorido-phosphate using silver(I) oxide in methanol. The C-Ag-C angle in the cation is 178.1 (2)°, and the N-C-N angles are 101.1 (4) and 100.5 (4)°. The meth-oxy groups adopt an anti conformation. In the crystal, anions (A) are sandwiched between cations (C) in a layered arrangement {C…A…C} n stacked along [001]. Within a C…A…C layer, the hexafluoridophosphate anions accept seve ...[more]