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Crystal structure of di-bromido-tetra-kis(propan-2-ol-?O)nickel(II).

ABSTRACT: The asymmetric unit of the mononuclear title complex, [NiBr2(C3H8O)4], comprises a Ni(II) cation located on a centre of inversion, one Br(-) anion and two propan-2-ol ligands. The Ni(II) cation exhibits a distorted trans-Br2O4 environment. There are O-H?Br hydrogen bonds connecting neighbouring mol-ecules into rows along [100]. These rows are arranged in a distorted hexa-gonal packing and are held together by van der Waals forces only.

SUBMITTER: Lv Y

PROVIDER: S-EPMC4719865 | biostudies-other | 2015 Dec

REPOSITORIES: biostudies-other

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Crystal structure of di-bromido-tetra-kis(propan-2-ol-κO)nickel(II).

Lv Yaokang Y Liu Mingxian M Ji Lvlv L Zhang Cheng C Ouyang Mi M

Acta crystallographica. Section E, Crystallographic communications 20151219 Pt 12

The asymmetric unit of the mononuclear title complex, [NiBr2(C3H8O)4], comprises a Ni(II) cation located on a centre of inversion, one Br(-) anion and two propan-2-ol ligands. The Ni(II) cation exhibits a distorted trans-Br2O4 environment. There are O-H⋯Br hydrogen bonds connecting neighbouring mol-ecules into rows along [100]. These rows are arranged in a distorted hexa-gonal packing and are held together by van der Waals forces only. ...[more]

PMID: 26870456

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