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Crystal structure of (5Z)-5-(5-bromo-2-hy-droxy-benzyl-idene)-1,3-thia-zolidine-2,4-dione.

ABSTRACT: In the title compound, C10H6BrNO3S, the dihedral angle between the thia-zolidine ring (r.m.s. deviation = 0.014?Å) and the benzene ring is 5.78?(14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N-H?O hydrogen bonds generate R 2 (2)(8) loops. The dimers are linked into [001] ribbons by pairwise O-H?O hydrogen bonds with R 2 (2)(18) motifs. There are no short contacts involving the Br atom.

SUBMITTER: Mague JT 

PROVIDER: S-EPMC4719880 | biostudies-other | 2015 Dec

REPOSITORIES: biostudies-other

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Crystal structure of (5Z)-5-(5-bromo-2-hy-droxy-benzyl-idene)-1,3-thia-zolidine-2,4-dione.

Mague Joel T JT   Mohamed Shaaban K SK   Akkurt Mehmet M   Younes Sabry H H SH   Albayati Mustafa R MR  

Acta crystallographica. Section E, Crystallographic communications 20151107 Pt 12

In the title compound, C10H6BrNO3S, the dihedral angle between the thia-zolidine ring (r.m.s. deviation = 0.014 Å) and the benzene ring is 5.78 (14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R 2 (2)(8) loops. The dimers are linked into [001] ribbons by pairwise O-H⋯O hydrogen bonds with R 2 (2)(18) motifs. There are no short contacts involving the Br atom. ...[more]

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