Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Proton-conducting Micro-solid Oxide Fuel Cells with Improved Cathode Reactions by a Nanoscale Thin Film Gadolinium-doped Ceria Interlayer.

ABSTRACT: An 8 nm-thick gadolinium-doped ceria (GDC) layer was inserted as a cathodic interlayer between the nanoscale proton-conducting yttrium-doped barium zirconate (BZY) electrolyte and the porous platinum cathode of a micro-solid oxide fuel cell (μ-SOFC), which has effectively improved the cathode reaction kinetics and rendered high cell power density. The addition of the GDC interlayer significantly reduced the cathodic activation loss and increased the peak power density of the μ-SOFC by 33% at 400 °C. The peak power density reached 445 mW/cm(2) at 425 °C, which is the highest among the reported μ-SOFCs using proton-conducting electrolytes. The impressive performance was attributed to the mixed protonic and oxygen ionic conducting properties of the nano-granular GDC, and also to the high densities of grain boundaries and lattice defects in GDC interlayer that favored the oxygen incorporation and transportation during the oxygen reduction reaction (ORR) and the water evolution reaction at cathode.

SUBMITTER: Li Y

PROVIDER: S-EPMC4770875 | biostudies-other | 2016

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Evaluation of the Effect of Sulfur on the Performance of Nickel/Gadolinium-Doped Ceria Based Solid Oxide Fuel Cell Anodes.

Project description:The focus of this study is the measurement and understanding of the sulfur poisoning phenomena of Ni/gadolinium-doped ceria (CGO) based solid oxide fuel cells (SOFC). Cells with Ni/CGO10 and NiCu5/CGO40 anodes were characterized by using impedance spectroscopy at different temperatures and H2 /H2 O fuel ratios. The short-term sulfur poisoning behavior was investigated systematically at temperatures of 800-950 °C, current densities of 0-0.75 A cm-2 , and H2 S concentrations of 1-20 ppm. A sulfur poisoning mitigation effect was observed at high current loads and temperatures. The poisoning behavior was reversible for short exposure times. It was observed that the sulfur-affected processes exhibited significantly different relaxation times that depend on the Gd content in the CGO phase. Moreover, it was demonstrated that the capacitance of Ni/CGO10 anodes is strongly dependent on the temperature and gas-phase composition, which reflects a changing Ce3+ /Ce4+ ratio.

| S-EPMC5324695 | biostudies-literature

Inkjet Printing Infiltration of the Doped Ceria Interlayer in Commercial Anode-Supported SOFCs.

Project description:Single-step inkjet printing infiltration with doped ceria Ce0.9Ye0.1O1.95 (YDC) and cobalt oxide (CoxOy) precursor inks was performed in order to modify the properties of the doped ceria interlayer in commercial (50 × 50 × 0.5 mm3 size) anode-supported SOFCs. The penetration of the inks throughout the La0.8Sr0.2Co0.5Fe0.5O3-δ porous cathode to the Gd0.1Ce0.9O2 (GDC) interlayer was achieved by optimisation of the inks' rheology jetting parameters. The low-temperature calcination (750 °C) resulted in densification of the Gd-doped ceria porous interlayer as well as decoration of the cathode scaffold with nanoparticles (~20-50 nm in size). The I-V testing in pure hydrogen showed a maximum power density gain of ~20% at 700 °C and ~97% at 800 °C for the infiltrated cells. The latter effect was largely assigned to the improvement in the interfacial Ohmic resistance due to the densification of the interlayer. The EIS study of the polarisation losses of the reference and infiltrated cells revealed a reduction in the activation polarisations losses at 700 °C due to the nano-decoration of the La0.8Sr0.2Co0.5Fe0.5O3-δ scaffold surface. Such was not the case at 800 °C, where the drop in Ohmic losses was dominant. This work demonstrated that single-step inkjet printing infiltration, a non-disruptive, low-cost technique, can produce significant and scalable performance enhancements in commercial anode-supported SOFCs.

| S-EPMC8622447 | biostudies-literature

Europium-Doped Ceria Nanowires as Anode for Solid Oxide Fuel Cells.

Project description:CeO2-based materials have been studied intensively as anodes for intermediate temperature solid oxide fuel cells (IT-SOFCs). In this work, pristine and europium (Eu)-doped CeO2 nanowires were comprehensively investigated as anode materials for IT-SOFCs, by a combination of theoretical predictions and experimental characterizations. The results demonstrate: (1) Oxygen vacancies can be energetically favorably introduced into the CeO2 lattice by Eu doping; (2) The lattice parameter of the ceria increases linearly with the Eu content when it varies from 0 to 35 mol.%, simultaneously resulting in a significant increase in oxygen vacancies. The concentration of oxygen vacancies reaches its maximum at a ca. 10 mol.% Eu doping level and decreases thereafter; (3) The highest oxygen ion conductivity is achieved at a Eu content of 15 mol.%; while the 10 mol.% Eu-doped CeO2 sample displays the highest catalytic activity for H2-TPR and CO oxidization reactions. The conducting and catalytic properties benefit from the expanded lattice, the large amount of oxygen vacancies, the enhanced reactivity of surface oxygen and the promoted mobility of bulk oxygen ions. These results provide an avenue toward designing and optimizing CeO2 as a promising anode for SOFCs.

| S-EPMC7261932 | biostudies-literature

Polycrystalline nanowires of gadolinium-doped ceria via random alignment mediated by supercritical carbon dioxide.

Project description:This study proposes a seed/template-free method that affords high-purity semiconducting nanowires from nanoclusters, which act as basic building blocks for nanomaterials, under supercritical CO2 fluid. Polycrystalline nanowires of Gd-doped ceria (Gd-CeO2) were formed by CO2-mediated non-oriented attachment of the nanoclusters resulting from the dissociation of single-crystalline aggregates. The unique formation mechanism underlying this morphological transition may be exploited for the facile growth of high-purity polycrystalline nanowires.

| S-EPMC3622141 | biostudies-literature

Single junction inverted polymer solar cell reaching power conversion efficiency 10.31% by employing dual-doped zinc oxide nano-film as cathode interlayer.

Project description:We present high efficiency and stable inverted PSCs (i-PSC) by employing sol-gel processed simultaneously doped ZnO by Indium and fullerene derivative (BisNPC60-OH) (denoted as InZnO-BisC60) film as cathode interlayer and PTB7-Th:PC71BM as the active layer (where PTB7-Th is a low bandgap polymer we proposed previously). This dual-doped ZnO, InZnO-BisC60, film shows dual and opposite gradient dopant concentration profiles, being rich in fullerene derivative at the cathode surface in contact with active layer and rich in In at the cathode surface in contact with the ITO surface. Such doping in ZnO not only gives improved surface conductivity by a factor of 270 (from 0.015 to 4.06 S cm(-1)) but also provides enhanced electron mobility by a factor of 132 (from 8.25*10(-5) to 1.09*10(-2) cm(2) V(-1) s(-1)). The resulting i-PSC exhibits the improved PCE 10.31% relative to that with ZnO without doping 8.25%. This PCE 10.31% is the best result among the reported values so far for single junction PSC.

| S-EPMC4212227 | biostudies-other

In Situ Nanoscale Dynamics Imaging in a Proton-Conducting Solid Oxide for Protonic Ceramic Fuel Cells.

Project description:Hydrogen fuel cells and electrolyzers operating below 600 °C, ideally below 400 °C, are essential components in the clean energy transition. Yttrium-doped barium zirconate BaZr0.8 Y0.2 O3-d (BZY) has attracted a lot of attention as a proton-conducting solid oxide for electrochemical devices due to its high chemical stability and proton conductivity in the desired temperature range. Grain interfaces and topological defects modulate bulk proton conductivity and hydration, especially at low temperatures. Therefore, understanding the nanoscale crystal structure dynamics in situ is crucial to achieving high proton transport, material stability, and extending the operating range of proton-conducting solid oxides. Here, Bragg coherent X-ray diffractive imaging is applied to investigate in situ and in 3D nanoscale dynamics in BZY during hydration over 40 h at 200 °C, in the low-temperature range. An unexpected activity of topological defects and subsequent cracking is found on a nanoscale covered by the macroscale stability. The rearrangements in structure correlate with emergent regions of different lattice constants, suggesting heterogeneous hydration. The results highlight the extent and impact of nanoscale processes in proton-conducting solid oxides, informing future development of low-temperature protonic ceramic electrochemical cells.

| S-EPMC9443464 | biostudies-literature

Cu - Nitrogen doped graphene (Cu–N/Gr) nanocomposite as cathode catalyst in fuel cells – DFT study

Project description:Novel Cu-nitrogen doped graphene nanocomposite catalysts are developed to investigate the Cu-nitrogen doped fuel cell cathode catalyst. Density functional theory calculations are performed using Gaussian 09w software to study the oxygen reduction reaction (ORR) on Cu-nitrogen doped graphene nanocomposite cathode catalyst in low-temperature fuel cells. Three different nanocomposite structures Cu2–N6/Gr, Cu2–N8/Gr and Cu–N4/Gr were considered in the acidic medium under standard conditions (298.15 K, 1 atm) in order to explore the properties of the fuel cell. The results showed that all structures are stable at the potential range 0–5.87 V. Formation energy, Mulliken charge and HOMO-LUMO energy calculations showed that Cu2–N6/Gr and Cu2–N8/Gr are more stable structure-wise, while free energy calculations showed that only Cu2–N8/Gr and Cu–N4/Gr structures support spontaneous ORR. The maximum cell potential under standard conditions was shown at 0.28 V and 0.49 V for Cu2–N8/Gr and Cu–N4/Gr respectively. From the calculations, the Cu2–N6/Gr and Cu2–N8/Gr structures are less favorable in H2O2 generation; however, Cu–N4/Gr showed the potential for H2O2 generation. In conclusion, Cu2–N8/Gr and Cu–N4/Gr are more favorable to ORR than Cu2–N6/Gr. Graphical abstract Image 1 Highlights • Novel Cu2–N6/Gr, Cu2–N8/Gr motifs investigated.• Cu2–N6/Gr, Cu2–N8/Gr are more stable than Cu–N4/Gr.• Cu2–N8/Gr, Cu–N4/Gr showed spontaneous ORR.• Inferior probability of H2O2 formation.• Maximum cell potential reached 0.49 V.

| S-EPMC10195903 | biostudies-literature

A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 °C.

Project description:The slow activity of cathode materials is one of the most significant barriers to realizing the operation of solid oxide fuel cells below 500 °C. Here we report a niobium and tantalum co-substituted perovskite SrCo0.8Nb0.1Ta0.1O3-δ as a cathode, which exhibits high electroactivity. This cathode has an area-specific polarization resistance as low as ∼0.16 and ∼0.68 Ω cm2 in a symmetrical cell and peak power densities of 1.2 and 0.7 W cm-2 in a Gd0.1Ce0.9O1.95-based anode-supported fuel cell at 500 and 450 °C, respectively. The high performance is attributed to an optimal balance of oxygen vacancies, ionic mobility and surface electron transfer as promoted by the synergistic effects of the niobium and tantalum. This work also points to an effective strategy in the design of cathodes for low-temperature solid oxide fuel cells.

| S-EPMC5216129 | biostudies-literature

Cobalt-Doped Carbon Nitride Frameworks Obtained from Calcined Aromatic Polyimines as Cathode Catalyst of Anion Exchange Membrane Fuel Cells.

Project description:Cobalt-doped carbon nitride frameworks (CoNC) were prepared from the calcination of Co-chelated aromatic polyimines (APIM) synthesized from stepwise polymerization of p-phenylene diamine (PDA) and o-phthalaldehyde (OPAl) via Schiff base reactions in the presence of cobalt (II) chloride. The Co-chelated APIM (Co-APIM) precursor converted to CoNC after calcination in two-step heating with the second step performed at 100 °C lower than the first one. The CoNCs demonstrated that its Co, N-co-doped carbonaceous framework contained both graphene and carbon nanotube, as characterized by X-ray diffraction pattern, Raman spectra, and TEM micropictures. CoNCs also revealed a significant ORR peak in the current-voltage polarization cycle and a higher O2 reduction current than that of commercial Pt/C in a linear scanning voltage test in O2-saturated KOH(aq). The calculated e-transferred number even reaches 3.94 in KOH(aq) for the CoNC1000A900 cathode catalyst, which has the highest BET surface area of 393.94 m2 g-1. Single cells of anion exchange membrane fuel cells (AEMFCs) are fabricated using different CoNCs as the cathode catalysts, and CoNC1000A900 demonstrates a peak power density of 374.3 compared to the 334.7 mW cm-2 obtained from the single cell using Pt/C as the cathode catalyst.

| S-EPMC8779780 | biostudies-literature

Preparation and Application of Fe-N Co-Doped GNR@CNT Cathode Oxygen Reduction Reaction Catalyst in Microbial Fuel Cells.

Project description:Through one-step pyrolysis, non-noble-metal oxygen reduction reaction (ORR) electrocatalysts were constructed from ferric trichloride, melamine, and graphene nanoribbon@carbon nanotube (GNR@CNT), in which a portion of the multiwall carbon nanotube is unwrapped/unzipped radially, and thus graphene nanoribbon is exposed. In this study, Fe-N/GNR@CNT materials were used as an air-cathode electrocatalyst in microbial fuel cells (MFCs) for the first time. The Fe-N/C shows similar power generation ability to commercial Pt/C, and its electron transfer number is 3.57, indicating that the ORR process primarily occurs with 4-electron. Fe species, pyridinic-N, graphitic-N, and oxygen-containing groups existing in GNR@CNT frameworks are likely to endow the electrocatalysts with good ORR performance, suggesting that a GNR@CNT-based carbon supporter would be a good candidate for the non-precious metal catalyst to replace Pt-based precious metal.

| S-EPMC7912981 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data