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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)zinc.

ABSTRACT: The Zn(II) atom in the title complex, [ZnCl2(C4H6N2S2)2], is coordinated in a distorted tetra-hedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyano-dithio-imino-carbonate ligands. In the crystal, the complex mol-ecules are connected through C-H?Cl hydrogen bonds and Cl?S contacts, leading to a two-dimensional structure extending parallel to the ab plane.

SUBMITTER: Diop MB 

PROVIDER: S-EPMC4778821 | biostudies-other | 2016 Mar

REPOSITORIES: biostudies-other

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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)zinc.

Diop Mouhamadou Birame MB   Diop Libasse L   Oliver Allen G AG  

Acta crystallographica. Section E, Crystallographic communications 20160224 Pt 3

The Zn(II) atom in the title complex, [ZnCl2(C4H6N2S2)2], is coordinated in a distorted tetra-hedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyano-dithio-imino-carbonate ligands. In the crystal, the complex mol-ecules are connected through C-H⋯Cl hydrogen bonds and Cl⋯S contacts, leading to a two-dimensional structure extending parallel to the ab plane. ...[more]